Bimetallic catalysis is a promising way to tune the catalytic properties of heterogeneous catalysts. In particular, bimetallic catalysts are extensively used to enhance the selectivity of monometallic catalysts in a variety of contexts, from oxidation catalysis to oxygenate coupling. In this work, we investigate PdxCuy/SiO2 and PdxAgy/SiO2 catalysts in the...
Mg-MOF-74 is one type of metal-organic frameworks (MOFs) that is widely known for its excellent CO2 uptake capacity. More intriguingly, it can be used to detect low levels of toxic gas such as CO2. Currently, most research into Mg-MOF-74 focuses on using the powder type as a CO2 absorbent because...
The continuous development of higher performing battery materials has emerged in parallel with the development of new manufacturing processes. Nanomaterials are one solution to addressing the cycling and performance challenges that limit existing battery cells. However, many of the methods used today for nanomaterial synthesis are high temperature batch methods...
Copper zinc tin sulfide (CZTS) is a potential solar material for thin film solar cells according to its suitable band gap in the visible light range, high absorption coefficient, low toxicity, good photostability and relative earth abundance of component elements. However, the production cost of this solar thin film material...
Modification of microbial electrolysis cells (MECs) by altering the sizes of the anode and the cathode, or their interaction with the liquid stream affects the performance of the MEC, but it remains difficult to quantify how much each change will contribute to the overall performance. Through this study, a method...
Covalent organic frameworks (COFs) are an emerging type of microporous crystalline polymers connected by organic units via strong covalent bonds. Due to the well-defined crystalline structure and excellent chemical and thermal stabilities, COF materials are being considered as promising candidates in a variety of applications, such as gas adsorption, catalysis...
Heterogeneous catalysis modulates the rate and selectivity of reaction processes by
stabilizing a series of intermediate states on solid surfaces, facilitating the production
of many commodity chemicals modern society relies upon. Conventional, thermal
catalytic processes—conducted at elevated temperatures and pressures—source
thermal, mechanical, and chemical potential energy from carbon-hydrogen bonds—
combustion...
It is desirable for complex engineered systems to perform missions efficiently and economically, even when these missions' complex, variable, long-term operational profiles make it likely for hazards to arise. It is thus important to design these systems to be resilient so that they will actively prevent and recover from hazards...
Greenland ice core water isotopic composition (δ¹⁸O) provides detailed evidence for abrupt climate changes, but is by itself insufficient for quantitative reconstruction of past temperatures and their spatial patterns. We investigate Greenland temperature evolution during the last deglaciation using independent reconstructions from three ice cores and simulations with a coupled...
Resistance against Bean common mosaic virus (BCMV) in Phaseolus vulgaris is governed by six recessive resistance alleles at four loci. One of these alleles, bc-3, is able to protect P. vulgaris against all BCMV strains and against other potyviruses; bc-3 was identified as the eIF4E allele carrying mutated eukaryotic translation...