Sulfoxide-ligand exchange (SLE) and asymmetric halogen-metal exchange (AHME) processes were separately examined for the enantioselective synthesis of functionalized alpha-haloalkylmetal (carbenoid) reagents. Carbenoids derived from SLE were used to effect stereospecific reagent-controlled homologation (StReCH) of boronic esters and those generated via AHME were engaged in Darzens-type chemistry with aldehydes.
Abstract for...
Characterizing stakeholder behavior when making decisions in watershed management is a great challenge for planners, not only because plans are associated with physical uncertainties but also because stakeholders’ behaviors are influenced by numerous factors. Since stakeholders’ decision-making is linked to multiple types of uncertainty, communication of uncertainty to stakeholders by...
Marginalized groups in the United States are often diagnosed with hypertension at younger ages, contributing to their excess burden of cardiovascular disease. These disparities in blood pressure control do not appear to be fully accounted for by individual risk factors, such as health behaviors or genetic differences. Experiences of discrimination...
Emergence of highly accurate Convolutional Neural Networks (CNNs) with the capability to process large datasets, has led to their popularity in many applications, including safety/security-sensitive (e.g. disease recognition, self-driving cars). Despite the high accuracy of convolutional neural networks, they have been found to be susceptible to adversarial noise added to...
The practice of green infrastructure is synonymous with collaborative partnerships. Expertise from engineers, land care professionals, planners, and natural resource consultants are often required for successful project implementation. Traditionally, these professionals perform their responsibilities in their disciplinary “silos,” but this evolving area of sustainable development is creating a demand for...
The purpose of this study was to understand the experiences of single fathers attending a community college. Single fathers comprise one-fifth of all single parent families, yet little research has been done on this growing segment of the population. A phenomenological approach was utilized to examine the attributes, needs, and...
A benthic microbial fuel cell (BMFC) is an electrochemical device that
generates current from the redox gradient at the sediment-water interface. Early
prototypes had anodes buried in anoxic sediments and cathodes in overlying water.
The BMFCs described in this dissertation are based on a chamber design that enables
the use...
A transient code (TFETC) for calculating the temperature
distribution throughout the radial and axial positions of a
thermionic fuel element (TFE) has been successfully developed.
It accommodates the variations of temperatures, thermal power,
electrical power, voltage, and current density throughout the
TFE as a function of time as well as...