The infrared spectra of the metaborate monomer and trimer
ions in NaC1, KC1, and KBr were studied. These spectra contain
bands due to the trimer in solid solution, in a second phase of the appropriate
potassium or sodium salt, and perhaps on adjacent lattice
sites. Furthermore, complex equilibria exist between...
Problems with aluminosilicate scales in pulp and paper recycle streams create an
interest in the formation mechanism and the chemical equilibrium of aluminosilicates.
Evaluating solubility data from a system containing Na⁺ CI⁻, and OH⁻ ions as well
as aluminium and silicon compounds, allowed to elucidate the characteristics of the
aluminosilicate...
Non-process elements are present in all kraft
recovery systems. Non-process elements are defined as
those elements which are not essential to the chemical
process, i.e., are neither active pulping chemicals (e.g.,
NaOH and Na₂S in the kraft process), nor compounds present
as a result of incomplete conversion of makeup chemicals...
A survey of the pulping literature indicated
that although the kinetics of the Kraft Pulping
process has been studied in detail , very few studies
have been reported for Alkaline Sulfite /
Anthraquinone (ASAQ) pulping process. There is no
existing rate model for this pulping process. Hence,
the objectives of...
Chemical equilibrium is a major factor in many natural and
industrial systems. The ability to predict ionic equilibrium is
extremely valuable in industry in solving problems without the costs
involved in full scale experiments. An example of an application in
the pulp and paper industry is the prediction of non-process...
Black liquor gasification is one of the promising alternatives to
eliminate the drawbacks of the conventional recovery unit of the
kraft process. A numerical model has been developed to simulate an
industrial pilot scale entrained-flow gasifier currently operating at
Tampere, Finland. The objective of the model is to investigate the...
Combustion properties of kraft black liquor solids were studied using a laminar entrained flow reactor. The tendency of black liquors to release fume (compounds containing Na⁺, K⁺, Cl⁻, SO₄²⁻, SO₃²⁻, S₂0₃²⁻ and C0₃²⁻) during combustion were observed at 1000°C. Black liquor solids with a size fraction of 63 to 100...
In this research a model is developed to predict population for relatively
rural areas experiencing rapid economic development. Of the many
ways to predict population size, in this research a "demographic-economic"
model is chosen for use. The economic variables which aid in projecting
population are total employment, and net changes...
For many resource-based communities throughout Oregon the timber
industry plays an important role. In many of these areas, federal
land holdings comprise a large proportion of the area's land holdings.
Management decisions regarding resource use on the National Forest
lands can have a major influence on the stability of local...
Competitive bid sales of U.S. Forest Service in the Pacific Northwest
timber resources have significant effects on the economies of
Oregon, Washington, and Idaho. These sales contribute to the economic
vitality of small regions or communities dependent upon timber as a primary
resource input. Any changes in the price or...
The source and nature of permit value and the federal grazing fee debate motivated this dissertation research. There is little doubt that federal grazing permits have value throughout the western United States, but the source of permit value is unclear. A traditional explanation focuses on the capitalized differential between the...
A rapid expansion of population and industrialization in recent
years has created new and difficult problems in water resources
management. Prudent management of water quality will require that
more efficient methods be developed for evaluating large volumes of
data on complex river systems, and tabulating the results in a form...
Solubility studies on the heavy metal sulfides in liquid hydrogen
sulfide at room temperature were carried out using the isopiestic
method. The results were compared with earlier work and with a
theoretical result based on Raoult's Law. A relative order for the
solubilities of sulfur and the sulfides of tin,...
A comparison was made of the d.c. conductivity of KCI:Pb²⁺
and KCl:PbO single crystals at temperatures greater than 325°C.
The energy of activation was 0.72 ev for all crystals. Lead concentration
was determined by chemical, optical and electrical methods. The
half band width of the UV absorption band at 273...
The simultaneous diffusion of Ca 2+ and Sr 2+ ions in purified
single crystals of KC1 and NaC1 was studied over the temperature
ranges from 451°C to 669°C in KC1 and from 448°C to 683°C in NaCl.
A radioactive tracer technique was used in two types of measurements:
diffusion from...
Since the early 1950's, the distribution of sediment at the
mouth of Redwood Creek has been altered by the effects of channel
aggradation and channelization along the lower reach. Severe flooding
in 1953, 1955, and 1964 caused bank erosion, landsliding, and
channel geometry changes along Redwood Creek. The increased sediment...
The Mount St. Helens eruption of May 18, 1980, offered an
excellent setting for evaluating early response of ecosystems to
disturbance. Prior to the eruption, the area was densely forested
with fir, hemlock, and Douglas-fir, and various understory species.
During the course of the eruption, hillslopes within a 180 degree...
Slow moving earthflows (0.1 15 m/yr.) may constrict valley
floors and directly impinge on stream channels. Earthflows that
move laterally into channels deliver organic and inorganic material
to the stream from the earthflow toe. If the amount and particle
size of this material is too large to be removed by...
A descriptive model of the routing of sediment that was
delivered to the study area by the 1980 eruptions of Mount St.
Helens has been developed. On hillslopes this sediment was
distributed among three major storage compartments: 1) the tephra
profile, 2) primary storage, and 3) secondary storage. The most...
The research undertaken in this study deals with three topics related to the prediction of thermodynamic properties of electrolytes in aqueous solutions. In the first, Pitzer ion interaction parameters for 304 single electrolytes were evaluated from recently published osmotic coefficient data at 25°C by using multiple regression analysis to fit...
In designing a solubility based separation process
for solvent recovery of an organosolv pulping process, the
phase behavior of polymeric lignin molecules in alcohol -
water mixed solvent should be known. In this study,
sodium lignin sulfonates (NaLS) samples were fractionated
into three different molecular weight fractions using a
partial...
The movement characteristics of five landslides are
compared and interpreted based on records of approximately
10-years duration. Condon landslide in the Oregon Coast
Range has consistently exhibited brief (1 - 8 days) movement
episodes in wet winter months, separated by long periods of
no movement. The translatory movement is probably...
Timber management of coastal watersheds in southwest Oregon has
been complicated by the need to protect anadromous fish habitat from
accelerated stream sedimentation resulting from management activity.
The rugged terrain of the Elk and Sixes River basins is underlain by
the complex geological province of the Klamath Mountains, in which...
The non-ideal aqueous electrolyte simulator (NAELS) is composed of
three major parts: a Newton-Raphson non-linear optimization program written
by Weare, et al (1987); an activity coefficient subroutine for non-ideal
electrolyte systems based on Pitzer's model; and an extensive, user expandable
database. It is robust, stable, and requires neither thermodynamic data...
This study develops an improved method for understanding
economic production relationships in small scale
fisheries. This method postulates that gross revenue is a
function of physical input quantities, and is based upon
the transcendental logarithmic function to derive factor
share equations for each of the five inputs in the model....
Fishing firms in Oregon operate in a complex and dynamic physical, biological and institutional environment. Within this environment, managers of these firms will attempt to maximize some objective function which may include profit. This maximization is dependent upon the level of output, or the levels of inputs. Given a relationship...
An econometric model of the canned tuna market is used to evaluate biased and unbiased estimators. Four methods for improving mean square error when multicollinearity is present in a regression equation are examined and compared with the results of ordinary least squares (OLS). Exact and inexact prior information methods are...
Linear programming is now widely accepted and used by researchers and industrial management people, but its adoption by farm managers has been slow. This study concentrates on the development of improved data transmittal techniques for farm organization linear programming. The program model is designed to analyze crop production alternatives. Models...
Questionnaires were mailed to farmers in six counties of the
Willamette Valley requesting the kind and size of enterprises and the
gross income received from the enterprises on each farm.
Enterprises were defined both as general livestock or crop categories
and as individual crop or livestock enterprises. Two computer
programs...
Various types of mass movement features are found in the drainage
basin of the East Fork Coquille River in the southern Oregon Coast
Range. The distribution and forms of mass movement features in the area
are related to geologic factors and the resultant topography.
The Jurassic Otter Point Formation, a...
Fire history and fire regimes were reconstructed for a 450 km² area in the central
western Oregon Cascades, using tree-ring analysis of fire scars and tree origin years at
137 sampled clearcuts. I described temporal patterns of fire frequency, severity, and size,
and interpreted topographic influences on fire frequency and...
A simple debris-slide model, employing a digital elevation model (DEM) and geological data, was used in a geographic information system (GIS) to map slope stability in the Andrews Experimental Forest, located in the western Cascade Range in Oregon, USA. To evaluate the contribution of error in elevation to the uncertainty...
Seasonal and annual patterns of N fluxes and concentrations in streamwater in six conifer-dominated watersheds at the H.J. Andrews Experimental Forest, OR, were studied to gain insight into the factors that influence N retention in this ecosystem. Processes affecting N flux in streamwater differed between organic (DON) and inorganic (DIN;...
This study examined debris flows occurring in a 125 km² study area in the Blue River watershed in the western Cascade Mountains of Oregon over a 50-year period. Debris flow occurrence was found to be concentrated in a distinct zone of high activity occupying approximately half of the study area,...
Changes in the concentrations of dissolved ammonia (NH4+1), nitrate (NO3-1), organic nitrogen (DON) were monitored along ground water flow paths to determine the importance of the ground water system to the stream nitrogen budget. The study site was located on a wide floodplain along a fourth-order
stream in the Oregon...
This study explored how selected input and redistribution processes affect the amount and arrangement of in-stream wood within the 64 km2 Lookout Creek watershed in the Andrews Forest, western Cascade Range, Oregon. A longitudinal inventory of in-stream wood was conducted over approximately 20 km of stream length in 2nd to...
Landforms sculpted by mass movements comprise much of the landscape in the Middle Santiam study area. Bedrock in the area is
mostly basalt and andesite flows and varied volcaniclastic rocks of the Little Butte Volcanic Series of Oligocene and early Miocene age, unconforniably overlain by andesite flows and tuffs of...
The increasing occurrence of aluminosilicate caused complications in krafi pulp mills can be attributed to the closing of purge points and the expanded use of contaminated feedstocks and recycled fiber sources. An active purge of aluminum and silicon from the chemical recovery cycle must be undertaken in order to maintain...
Descriptions of the fire regime in the Douglas-fir/western hemlock region of the Pacific Northwest traditionally have emphasized infrequent, predominantly stand-replacement fires and an associated linear pathway of stand development, where all stands proceed along a common pathway until reset by the next fire. Although such a description may apply in...
Disturbances are a prevalent and important part of ecosystems. Many landscape patterns that we find today were created, maintained, and changed by natural disturbance regimes. This is especially true for fire, which has historically been a common, natural disturbance in the western U.S forests and grasslands and many other parts...
The effects of incorporation of selected biocides on physical and mechanical properties of aspen strandboard were assessed using five copper-based preservatives or zinc borate at three retention levels. Tebuconazole or 4,5-dichloro-2-N-octyl-4-isothiazolin-3-one (DCOI) were added as co-biocides to selective copper-based treatments. Mold box tests showed that only panels treated with DCOI...
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_____________________________________________________________________
Jeffery J. Morrell Frederick A. Kamke
The effects of incorporation of selected biocides
The investigation
of impurity effects on the properties of alkali
halide crystals has often been difficult because of the variation of procedures used in various experiments.
The purpose of this work is to
develop a self consistent method of measuring the IV dipole polarization properties of single crystals while eliminating...
The development and applications of a 0.2 cm⁻¹ resolution
Nd-YAG laser powered coherent anti-Stokes Raman
spectroscopy, CARS, spectrometer for gas phase studies is
chronicled in this thesis. Applications including CARS
lineshape analysis, resonant CARS, and CARS of transient
species and excited state molecules is reported.
The intensity of the signal...
Morphological filters have shown good performance in various image processing applications. Furthermore, their algorithms are easy to implement in special architectures, with the exception that linear filtering cannot be implemented in many of these cases. In this study, a new architecture and corresponding algorithm, capable of realizing linear shiftinvariant filters,...
Mathematical models for the doubly-fed machine are
presented. The properties of the machine with rotor excitation as supplied by a power converter with voltage
source character are reviewed. The peculiar torque-speed
characteristic of the machine in this operating mode and
its effect on the stability of the machine are presented....
A variety of laser spectroscopic methods are employed in this
thesis research for studies of CF₃NO, an interesting model
photodissociative system, and for investigation of low energy rotations
and vibrations of small molecules and low molecular weight clusters in
free jet expansions.
Nonradiative energy decay for electronically excited CF₃NO is...
With the development of converters and inverters, it
became possible to control the stator current of an
induction motor. The differential equations which describe
transient behavior of the induction motor are conveniently
expressed by transforming the stator and rotor variables to
d-q axes rotating at synchronous speed. The transient
behavior...
A systematic optimization of the Cohen class time-frequency
transformation for detecting the parameters change is developed.
The local moments approach to change detection is proposed and a
general formula for the local moments is derived. The optimal
kernel functions of the time-frequency transformation are determined
based on the combined criteria...
Mathematical morphology, developed in the early 1960's for
single-component signals, has been applied to a number of image
processing applications. This investigation examines the systematic
extension of mathematical morphology to multi-variate signals.
Two approaches are considered. The first approach, the
extension of the theory of single-component morphological filters to
multi-variate...
The likelihood of a Cascadia Subduction Zone (CSZ) earthquake is estimated between 37 to 42% in the next 50 years, leading to strong shaking, liquefaction, landsliding, and other seismic ground failure resulting in major impacts to critical lifelines such as the western power grid. Electrical power is essential for continued...
This study evaluates the use and efficacy of biochar for treatment of source and nonpoint source pollutants in storm water. Biochar is the solid byproduct of incomplete combustion of biomass under low-oxygen and elevated temperature conditions (Keiluweit, 2010, Beesley and Dickinson, 2011, Bracmort, 2010). The source stock for tested biochar...
Spring chinook salmon, Oncorhynchus tshawytscha, in the Snake River Basin are listed as endangered under the Endangered Species Act. The typical life history of spring chinook salmon is semelparous. An experiment was performed to see if mature male spring chinook salmon parr could be reconditioned after hand-spawning and spawned in...
This dissertation describes the development of a new sustained release formulation of nifedipine. The new formulation was developed by coating commercially available immediate release soft elastic gelatin capsules using a spray coating technique with two different polymeric combinations. Dissolution studies were conducted and showed that controlled release of nifedipine was...
The overall objective of this study is to address questions concerning the long-term
mechanical strength of the lithosphere across the equatorial margin of Brazil. The
approach used in this study consists of calculating the frequency response function
estimates, also called admittance, using gravity and bathymetry data. These
experimental estimates are...
The influence of mycorrhizae on the nutrient uptake of
strawberries and red raspberries was investigated. On red raspberries
innoculation with a mycorrhizal fungus resulted in increased P uptake
and a greater concentration of P in the shoots of the plants. The
strawberries were innoculated with 2 species of mycorrhizal fungus....
A cultivar comparison study was conducted to identify similarities
and differences in cane characteristics between 2 primocane fruiting
red raspberry cultivars and to determine if the differences and
similarities can help determine cultural practices that may improve
productivity. The comparison of the cultivars 'Amity1 and 'August
Red' showed a difference...
A nifedipine sustained release dosage form was prepared by using hot-melt batch
coating. Substrates are sugar beads, mesh size 30-35. Stearic acid, Acid Triglyceride, and
carnauba wax were coating agents used to make single layer coated beads and multiple
layer coated beads containing nifedipine. Dissolution of nifedipine from the beads...
Riparian ecosystems play numerous and essential roles related to the quality and
flow of water, and food/habitat for fish, and varieties of wildlife. Due to lateral and linear linkages throughout the landscape, these zones influence the integrity of the terrestrial as well as the entire aquatic-riverine ecosystem. Since Euro-American settlement...
The first project of this thesis is an in vitro study. This study was performed with 8 hydrocortisone topical products on the market for the purpose of comparing one Tec Lab product, a Corticool gel, to the other seven common products on the market. The permeation of these products was...
