The goal of this dissertation is to develop a chronology of the retreat of the southern margin of the Scandinavian Ice Sheet (SIS) during the late Pleistocene using surface exposure dating with cosmogenic 10Be. A sequence of seven prominent moraines in northeastern Europe (the Leszno Moraine, the Pomeranian Moraine, the...
The last deglaciation of the Scandinavian Ice Sheet (SIS) from ∼21,000 to 13,000 yr ago is well-constrained by several hundred ¹⁰Be and ¹⁴C ages. The subsequent retreat history, however, is established primarily from minimum-limiting ¹⁴C ages and incomplete Baltic-Sea varve records, leaving a substantial fraction of final SIS retreat history...
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et al., 2009; Larsen et al., 32
2012; Linge et al., 2007; Mangerud et al., 2013; Rinterknecht et al
The last deglaciation of the Scandinavian Ice Sheet (SIS) from ∼21,000 to 13,000 yr ago is well-constrained by several hundred ¹⁰Be and ¹⁴C ages. The subsequent retreat history, however, is established primarily from minimum-limiting ¹⁴C ages and incomplete Baltic-Sea varve records, leaving a substantial fraction of final SIS retreat history...
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(ka) Internal Uncertainty (ka) Site mean age (ka) e,f
LGM moraine (from Rinterknecht et al., 2006)h
The last deglaciation of the Scandinavian Ice Sheet (SIS) from ∼21,000 to 13,000 yr ago is well-constrained by several hundred ¹⁰Be and ¹⁴C ages. The subsequent retreat history, however, is established primarily from minimum-limiting ¹⁴C ages and incomplete Baltic-Sea varve records, leaving a substantial fraction of final SIS retreat history...
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, Anders E. Carlson b, David J. Ullman b,
VincentR. Rinterknecht c,j, Glenn A. Milne d, Juha-Pekka Lunkka
The last deglaciation of the Scandinavian Ice Sheet (SIS) from ∼21,000 to 13,000 yr ago is well-constrained by several hundred ¹⁰Be and ¹⁴C ages. The subsequent retreat history, however, is established primarily from minimum-limiting ¹⁴C ages and incomplete Baltic-Sea varve records, leaving a substantial fraction of final SIS retreat history...
A novel approach for the colorimetric detection of creatinine in a paper/polycaprolactone hybrid microfluidic device using alkaline3,5-dinitrobenzoate (DNB) is described. The reaction parameters of reagent concentration, alkalinity, and analysis time are optimized for fast reaction times and high color yield. Microfluidic devices incorporating this assay are designed and fabricated to...
The concept of reducing laboratory operations in scale such that they fit on a microfluidic chip has been met with great enthusiasm. Lab-on-a-chip devices promise to be cost effective to operate due to reduced reagent consumption, have the potential to offer shorter analysis times due to their short path lengths,...
Two improvements to the established procedures for synthesis and response detection of ion-selective optical sensors (optodes) were introduced.
The first improvement addresses the drawback of organic dye (optode-localized chromoionophore) photobleaching. This positively impacts fluorescence response and allows for (1) direct measurement of hydrogen ion activity upon binding with the dye,...
The detection of biomolecules is critical for clinical diagnostics but requires specialty labor and high cost. The use of microfluidic paper-based analytical devices (µPADs) for bioassays is simpler and cheaper but has low sensitivity. Improved immobilization of antibodies onto cellulose is demonstrated through surface functionalization with APTES and glutaraldehyde. The...
In this comprehensive thesis, we present a series of experiments and findings that highlight the
critical importance of TDC Voltage Sensors in the hardware security domain. Our research begins
by introducing a novel self-calibrating module, demonstrating its efficiency through preliminary
calibration tests. We then delve into the Peak-to-Peak tests, which...
Voltage fault injection is a technique to disrupt power supply, such that the data or instruction flow in a microcontroller can be modified. Recently, a new class of voltage glitches was introduced termed arbitrary wave voltage glitches. Despite its demonstrated success in practical studies it comes with additional challenges, such...
Retention, the ability of an institution to retain students through degree completion, is a major concern for most colleges and universities. The current first to second year retention rate at Oregon State University (OSU) is about 80% (OUS 2008; 2011). Currently the OSU Strategic Plan includes the goal of increasing...
The development of microfluidic devices for heavy metal extraction is presented in this dissertation. Various research areas, covering subjects from photochromic compound syntheses to microchip fabrication techniques are explored to develop microfluidic devices capable of extracting heavy metal ions from drinking water. Through integration of the beneficial characteristics of both...
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Vincent T. Remcho
The development of microfluidic devices for heavy metal extraction is
NADPH-cytochrome P-450 reductase, an important enzyme in the
cytochrome P-450-dependent microsomal monooxygenase system, was
purified from insecticide-resistant (R) and -susceptible (S) house
flies (Musca domestica, L.) and from the black blow fly (Phormia
regina, Weigen). Proteolytic degradation to a P-450 - inactive form
of the reductase was reduced during the...
The dataflow model of computation differs from the traditional control-flow
model of computation in that it does not utilize a program counter to sequence
instructions in a program. Instead, the execution of instructions is based solely on the
availability of their operands. Thus, an instruction is executed in a dataflow...
There has been a tremendous growth in interest in carbon nanodots (C-dots) in the past several years. As a nascent nanomaterial, C-dots have shown great promise in applications that benefit from their superior water dispersibility, low toxicity, non-blinking fluorescent output, chemical and biological compatibility, ease of functionalization and resistance to...
Analytical chemistry is an area of chemistry primarily focused on the study and use of instruments for separation, identification, and quantification of an analyte of interest. Specifically, separation science within analytical chemistry often refers to the process of dividing mixtures into their small component parts based on differences in their...
Analytical techniques are utilized in a wide variety of applications. Traditionally, analytical measurements are achieved by trained personnel in a laboratory setting using expensive scientific instruments, which limits their applicability in resource-limited areas and point-of-care applications. Therefore, the concept of enabling these laboratory-based qualitative and quantitative assays in microfluidic device...
The concept of reducing laboratory operations into microfluidic devices has been an attractive area of research for several decades. Due to several advantages of porous-media microfluidic devices including low mass, portability, power-free fluid transport, and the ability to store dried reagents in the porous structures, these devices show great promise...
Since their discovery in the 1990s, the great potential of carbon nanotubes (CNTs) has made them a focus of many research endeavors, including their application as components of biosensors. The inherent chemical "inertness" of CNTs makes their application to biosensing a challenge. It is necessary to "decorate" their surfaces to...
The intriguing size- and shape dependent properties of nanoparticles have garnered recent attention in many science and engineering areas. When the particle size is in the nanometer size range, the material exhibits very different properties such as surface plasmon resonance (of gold nanoparticles) and superparamagnetism (of iron oxide nanoparticles). The...
Miniaturized and portable microfluidic analytical platforms have been widely explored in the broad field of chemical analysis. The concept of microfluidics offer a number of important advantages, including low reagent consumption, low-cost detection, high sample throughput, and shorter analysis time. Semiconductor nanocrystals or quantum dots have been extensively utilized in...
The development of micro total analysis systems (µTAS), also called “lab-on-a-chip”, or microfluidic analysis systems, is presented in this dissertation. Various research areas, covering subjects from magnetic particles synthesis to novel microchip fabrication techniques, are explored to develop a lab-on-a-chip system capable of performing magnetic bead-based bioassays. These devices are...
Dielectrophoresis (DEP) is a separation method in which a non-uniform electric
field is used to induce a dipole moment in a suspended particle. If the polarization
of the particle is greater than that of the suspending medium, the particle will move
towards the region of higher field strength (positive DEP);...
Continued interest in the development of miniaturized and portable analytical platforms necessitates the exploration of sensitive methods for the detection of trace analytes. Nanomaterials, on account of their unique physical and chemical properties, are not only able to overcome many limitations of traditional detection reagents but also enable the exploration...
Over the last decade, the miniaturization of analytical systems has become an increasingly important and interesting research area. Miniaturized systems offer many advantages, including reduced reagent and sample consumption, shorter analysis times, portability and disposability. This dissertation describes novel approaches in this direction, focusing on two areas: the miniaturization of...
Electrodeposition is a versatile polymer deposition technique to create nano-microscale materials using an electrical field generated from a charged droplet of solution and a grounded collector. Electrospinning or electrospraying can occur during electrodeposition, leading to the creation of nanofibers or bead-like materials depending on the process parameters. Photopolymerization of the...
The emerging field of nanotechnology strictly requires the micro-scaling of the available separation technology and the design of novel devices for separations of molecules of interest. The separation of proteins and nanoparticles is challenging due to their relatively large size, non-specific adherence to surfaces and instability in many solvents.
This...
Due to a number of disadvantages associated with the use of antibodies as
affinity stationary phases, researchers have recently began to explore the use of RNA
and DNA aptamers for use as affinity stationary phases. These molecules have been
shown to be a viable choice for applications in many methods...
High Performance Liquid Chromatography-Mass Spectrometry coupled with filtration, centrifugation, and other common sample preparation techniques offers a rapid and robust method for separating and quantifying propofol, a commonly used anesthetic, from human blood and its synthetic analogs. Method development is important for not only optimizing separation and quantification for a...
Capillary electrophoresis as a technique has many applications in a broad range of fields including forensics, environmental analysis, and biological analysis and as a separation method for samples such as oligonucleotides, peptides, proteins, and pharmaceuticals. The research conducted herein is for the antibiotic pharmaceutical ciprofloxacin HCl and three impurities. Sample...
The challenges prompted by miniaturization of chromatographic systems have led scientists to explore new avenues in the synthesis of stationary phases. Packed capillary columns have found limited application in routine analysis due to a number of technical difficulties, most of which are attributable to the frits. New column designs insure...
For a number of reasons, miniaturization of chromatographic columns has been a general trend over the past three decades. Methods designed to enhance selectivity and efficiency can offer improved separation power and speed, expanding on the advantages of miniaturized columns. This dissertation describes novel approaches in this direction, focusing on...
A microfluidic nanofiltration module has been designed, fabricated and applied to the continuous-flow, pressure-driven, post-synthetic purification of macromolecules and nanoparticles via diafiltration using a commercially available organic solvent resistant nanofiltration membrane, STARMEM 122. This module will readily interface with other microscale components within a
"nanofactory" for the rapid synthesis, purification...
Electrospinning and electrospray are both nano-scale material fabrication techniques, based on related phenomena of electrically charged fluid spray from a droplet of liquid. Material is dissolved in liquid, then a spray is generated by applying a high voltage, creating an electric field, between the fluid dispensing capillary and a grounded...
A system to reversibly extract Pb²⁺ ions from aqueous solutions using spiropyran functionalized nanofibers was proposed. Spiropyrans are photochromic compounds which undergo a conformational change that alters their physical properties and makes Pb²⁺ binding possible upon irradiation with UV light (365 nm). Irradiation with green light (525 nm) reverses this...
The Micralyne microfluidic toolkit (μTK) was an instrument built by Micralyne in the early 2000’s. It was built for electrophoresis and has a sensitive laser-induced fluorescence detection system. The updates to the system were upgrading the control GUI from running in LabVIEW 5 (Windows XP, 2000) to LabVIEW 2012 (Windows...
The development of simple, rapid, and sensitive methods for thiophenol detection is of great importance in various fields, including environmental monitoring and food quality. Here, we present a novel approach for the colorimetric detection of thiophenols using gold nanoparticles (AuNPs) as the sensing platform. AuNPs aggregate in the presence of...
A system of Photoactuated Droplet Microfluidics (PDM), in which a droplet of
fluid is moved by way of the manipulation of the wettability of a spiropyran
functionalized surface via irradiation with ultraviolet and visible light, was proposed. The
photochromic behaviors of several species of spiropyran were studied and a procedure...
The overall concept of reducing laboratory operations to a scale that fits on a single microfluidic chip has been an attractive area of research over the last several decades. Despite a surge in research, few commercial success stories have been written. Lab-on-a-chip technologies have the capability to be cost effective...
Gene synthesis is an important tool in molecular biology. However, the current
bench-top method of gene synthesis is a costly, time-intensive and reagent-consuming
process. Lab-on-chip technology has many benefits over current bench top methods.
Microchips consume smaller reagent volumes, are reusable and less expensive to make.
This thesis explores the...
The cross over from batch nanoparticle synthesis to continuous synthesis processes is crucial to the commercialization of these materials. This project reports comparative studies of batch and continuous synthese of copper nanoparticles by the polyol method. Continuous synthesis of copper nanoparticles was done utilizing a stainless steel micro-mixer that yielded...
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Vincent T. Remcho
The cross over from batch nanoparticle synthesis to continuous
We have developed a compact micro total analysis system (μTAS) to serve as a platform for in-situ spectrophotometric water quality monitoring. Individual fluidic, optical, and electrical components were designed, developed, and characterized. These components were combined in both an integrated (single lithographic “chip-based” platform) and a modular manner. The microfluidic...
Relative effects of light, nutrients, and grazing on primary production were investigated in streams in the Cascade Mountains of Oregon and in laboratory streams. Relative magnitudes of primary production and associated processes were examined for one year in a stream that flowed through a clearcut and an old-growth forest in...
Evolution, development and progress mark the pathway of mankind from the earliest history of the race to the present time. In art, science and literature, remarkable transformations have taken place; in habits, customs and modes of living; we have passed from the primitive conditions of wild, savage tribes to that...
A study has been made to investigate the fuel-cladding
mechanical interaction (FCMI) in sphere pac fuels.
An FCMI simulation has been constructed using the JVG
Apparatus. This model has been used to investigate the
mechanical interaction between a sphere pac bed and a
cladding wall in terms of the cladding...
The electrochemistry of cadmium at a Reticulated Vitreous
Carbon (RVC) electrode has been studied to determine the suitability of
RVC as a working electrode for the electrochemical preconcentration of
cadmium in the corrosive environment of zirconium dissolved in
hydrofluoric acid.
The electrochemistry in this investigation deals with deposition
of solid...
This work entails both imaging and therapeutic applications of biomedical optics. In both contexts, an understanding of light transport in tissues is necessary. An overview of optical transport in tissues is given, including scattering theory. Digital Fourier holographic microscopy is introduced and applied as a means of metrology via optical...
The purpose of this investigation was to test two hypotheses.
The first hypothesis interprets allochthonous rocks in the southern
Pinyon Range to lie on the Devonian Nevada Group. The second
hypothesis interprets allochthonous rocks to lie on the Mississippian
Dale Canyon Formation. Evidence presented here supports the second
hypothesis.
During...
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area, Elko and Eureka Counties, Nevada
AN ABSTRACT OF THE THESIS OF
Robert Vincent Visconti for the
The principal aim of this study was the use and evaluation of dynamic
modeling techniques to identify mathematical models for cereal drying rates and
quality changes that best describe thin-layer malt drying data. Seven thin-layer
malt drying experiments were performed at the Great Western Malting pilot
facilities, Vancouver, WA. Malt...
Barley yellow dwarf virus (BYDV) is a globally distributed pathogen of grasses that is transmitted by aphids. Little research has been done examining the response of aphids to different host grasses in naturally mixed communities. We measured the short-term fecundity of the aphid Rhopalosiphum padi, a widely distributed vector of...
The fishes of Upper Klamath Lake appeared to distribute
themselves in three general groups during the summers of 1964
and 1965: (1) the chubs--unrestricted as to distribution with slight
seasonal variations; (2) rainbow trout and yellow perch -- restricted
to certain water conditions that exist only along the northern marsh...
The ³²P material balance method for measuring periphyton production and grazing rates on periphyton in streams developed by Elwood and Nelson (1972) was evaluated by laboratory and field experiments. Three basic assumptions of the method were examined: 1) sloughing of periphyton from substrates is negligible, 2) sorption of ³²P onto...
A discrete multi-facility plant location algorithm developed by Basheer Khumawala is modified and applied to the location analysis of offices of the State of Oregon Health Facilities Licensing and Certification Section (HFLC). Choice of the algorithm is based upon a literature survey of available computational procedures which compares their relative...
The objective of this thesis is to examine and compare hot
metal and cold type production of display advertising for newspapers.
The classical hot metal system uses a lead alloy as its basic building
material while modern cold type production uses photographic
means. Some advantages of using cold type are...
The purpose of this research was to determine the role of formative experiences in the home and family pertaining to environment on children's overall environmental beliefs. Students attending environmentally related and non-environmentally related summer camps at a children's science museum served as test subjects in this study. A written instrument...
Some forms of bacterial respiration do not involve molecular
oxygen but instead utilize other hydrogen acceptors for oxidation
of the substrate. Various organic and inorganic acceptors may be
used. In the present study, the inorganic radicals, nitrate and
nitrite, were investigated. Preliminary evidence indicated that
nitrate and oxygen are able...
This study explores the context of and impacts resulting from a broad range of university student civic engagements on the city of Corvallis, Oregon. Through semi-structured interviews with local community partners who engage with the university in what I term student civic service-learning, feedback reveals impacts that are overwhelmingly positive,...
During construction of the embankment at Blue River Dam
placement difficulties were occasionally experienced with the filter
zone sands. In the extreme condition construction equipment became
mired and part of the fill had to be removed and wasted. A
laboratory investigation was conducted on materials from the above
project to...
The genus Deraeocoris Kirschbaum of western America north of
Mexico was revised. Approximately 10,000 specimens from the Nearctic
Region were examined. Taxonomic characters used by previous authors
were reevaluated. In addition to the male parameres, the male vesica
and the female posterior wall of the bursa copulatrix and sclerotized
rings...
The corvina reina (Cynoscion albus) is an important part of the artisanal fishery
in the Gulf of Nicoya, Costa Rica. Stock assessment on this sciaenid species has been
restricted to the use of length-based methods because of the lack of age data. Direct age
determination methodologies for tropical species often...
Current life cycle assessment tools are often deficient in assisting design for sustainable manufacturing efforts. Integrating an improved assessment method into a decision support framework will provide a means for designers and engineers to better understand the impacts of their decisions. A unit process modeling-based sustainability assessment method is presented...
Halogenated Polycyclic Aromatic Hydrocarbons (X-PAHs) are ubiquitous contaminants that are thought to be generated by processes such as chemical industries and incomplete combustion, including waste incineration and electronic waste (e-waste) burning. X-PAHs are a concern for environmental and human health because they are toxic, mutagenic, and are expected to be...
The objective of this study was to identify aroma volatiles in sweet whey powder. Volatiles were isolated by solvent extraction and solvent assisted flavor evaporation. Fractionation was followed to separate acidic volatiles from nonacidic volatiles. Gas chromatography/olfactometry and gas chromatography-mass spectrometry were used for the identification ofaroma compounds. Osme methodology...
In order to evaluate the shallow stratigraphy along the southern Cascadia abyssal margin and northern California abyssal plain, CHIRP subbottom profiles capable of imaging individual turbidite beds in the upper tens of meters of the subsurface were collected. Reflectors imaged with the 3.5 kHz CHIRP subbottom data represent turbidite beds...
Experiments were conducted with two strains of the coccolithophorid Emiliania huxleyi. Previous experiments with CCMP1742 and 372 at a light intensity of 60 µEin/m²-s showed that during five-day periods of continuous darkness, strain 1742 was taking up nitrate from the media while strain 372 was not. The nitrate uptake in...
The widespread adoption of computerized systems around the turn of the century as a means of more efficiently conducting elections introduced more issues than these computer systems were intended to address. Though many of these flaws were not considered for years or decades after the introduction of digital election infrastructure,...
Multi-party computation (MPC) is a field of study focused on devising cryptographic protocols that allow participants to learn the output of some function of their private inputs without trusting a third party to perform the computation. This is usually done at a large scale between data centers, with little emphasis...
Background: The Oregon Wrestling Weight Monitoring Program establishes the athlete’s minimum wrestling weight (MW) for the season. This program specifies the
wrestler’s maximum weight loss rate and was implemented in order to reduce
unhealthy weight-cutting behaviors commonly practiced by wrestlers. Aims: (1) To
compare differences in percent body fat (%BF)...
In a search for designed materials that mimic those found in biological systems, combining polymers with inorganic materials in sol-gel chemistry processes has gained momentum in the research world since the 1990's. This work methodically investigated the properties of several related polymer-SiO₂ hybrids prepared by a simple methodology that could...
This article presents the results of a high-resolution (1/12°), two-way nested simulation of the
oceanic circulation in the southwestern Atlantic region. A comparison between the model results and
extant observations indicates that the nested model has skill in reproducing the best-known aspects of the
regional circulation, e.g., the volume transport...
Observations show abrupt changes in the oceanic circulation of the southwestern Atlantic. These
studies report a southward drift of the Brazil/Malvinas Confluence (BMC) and a change in the spectral
characteristics of the Malvinas Current (MC) transport. We address the cause of these changes using the result
of a high-resolution numerical...
This paper examines the viability of the management of a transboundary resource, the Bay of Biscay anchovy (Engraulis encrasicolus L.). A deterministic model is used to simulate the anchovy dynamics, with the fish stock consisting of two age groups, “young" and “old", while recruitment follows a Beverton Holt pattern. Two...
A key issue in fisheries restoration is the speed at which recovery can occur, while still meeting the
economic and social constraints which managers must deal with. This paper uses the viable control approach to examine fisheries restoration and study the tradeoffs involved with the selection of recovery strategies. We...
There is growing recognition worldwide that the impacts of fishing on non-targeted components of marine ecosystems should be included in the assessment of fisheries sustainability. This leads to the inclusion of new constraints in evaluations of the long-term bio-economic performance of fisheries. In this paper, we analyze the implications of...