This paper provides a Total Allowable Catch (TAC) assessment model for a single gear, multi-species fishery in South Korea. To estimate appropriate Allowable Biological Catch (ABC) of mackerel and jack mackerel caught by the large purse seine fleet in the territorial waters of South Korea, the model uses an extended...
We report ultrafast pump-probe spectroscopy examining exciton dynamics in atomically thin MoS2. Spectrally and temporally resolved measurements are performed to investigate the interaction dynamics of two important direct-gap excitons (A and B) and their associated broadening kinetics. The two excitons show strongly correlated interexcitonic dynamic, in which the transient blue-shifted...
Compared to conventional amorphous silicon (a-Si) TFTs, amorphous metal oxide TFTs have superior device performance such as
higher mobility, better sub-threshold swing, and lower off-state current. Amorphous metal oxide TFTs have an additional advantage
on the device uniformity due to the lack of grain boundary issues in the poly-Si TFTs....
The diffusion behavior of arsenic (As) and gallium (Ga) atoms from semi-insulating GaAs (SI-GaAs) into ZnO films upon post-growth annealing vis-`a-vis the resulting charge compensation was investigated with the help of x-ray photoelectron spectroscopy (XPS) and secondary ion mass spectroscopy. The films, annealed at 600 °C and 700 °C showed...
The various solution-based processes, spin coating, inkjet printing, microreactor assisted nanoparticle deposition (MANDTM) and spin-successive ionic layer absorption and reaction (Spin-SILAR) were used to demonstrate thin film electronics and anti-reflective coatings. Several aspects of thin film transistors (TFTs) were tested including a range of temperatures, annealing atmosphere, and deposition methods....
School forests in South Korea are trees and vegetation areas within schoolyards, and they provide natural environments for schools and neighborhoods. After the Korea Forest Service (KFS) and local governments create these school forests, the management of school forests transfers to the host schools. Some studies suggest that experiences with...
The aim of the research undertaken for this thesis was to develop a new high-performance amorphous oxide semiconductor (AOS) for use as a channel layer in a thin-film transistor (TFT). AOS TFTs offer higher electron mobility than the established amorphous silicon based technology. A new channel material comprised of aluminum...
Phospholipase C-β (PLC-β) isozymes are key effectors in G protein-coupled
signaling pathways. Prior research suggested that some isoforms of PLC-β may exist
and function as dimers, but little is known about dimerization of PLC-β. Data from coimmunoprecipitation
assays of differentially-tagged PLC-β constructs and sizeexclusion
chromatography of native PLC-β support homodimerization...
A series of new ternary graphite intercalation compounds (GICs) containing alkaline earth metal cations (M = Mg, Ca, Sr, Ba) and ethylenediamine (en) are reported. These GICs are deep blue to green in color and can be prepared as phase-pure compounds by the direct reaction of graphite powder with the...
Metal–insulator–metal diodes with Nb₂O₅ and Ta₂O₅ insulators deposited via atomic layer deposition are investigated. For both Nb₂O₅ and Ta₂O₅, the dominant conduction process is established as Schottky emission at small biases and Frenkel–Poole emission at large biases. Fowler–Nordheim tunneling is not found to play a role in determining current versus...
In this work, stainless steel wire cloth (SSWC) for metallic support was thermally treated to increase the adhesive strength of Al₂O₃ by improving superficial roughness. After coating Al₂O₃ on SSWC, Pt particles as a catalytic component were deposited on the Al₂O₃/SSWC. These supports and catalysts were characterized by N₂ gas...
Peroxiredoxins (Prxs) are very effective peroxide reducing enzymes, but also are susceptible to being
oxidatively inactivated by their own substrates. The level of sensitivity to such hyperoxidation varies
depending both on the enzyme involved and the type of peroxide substrate. For some Prxs, the
hyperoxidation has physiological relevance, so it...
Nanostructured ZnO films were obtained via thermal oxidation of thin films formed with metallic Zn-nanoparticle dispersions. Commercial zinc nanoparticles used for this work were characterized by microscopic and thermal analysis methods to analyze the Zn-ZnO core shell structure, surface morphology and oxidation characteristics. These dispersions were spin-coated on SiO₂/Si substrates...
The trend towards higher resolution, faster refresh rate active-matrix liquid-crystal displays (AMLCDs) as well as the emergence of active-matrix organic light-emitting diode (AMOLED) displays is driving the demand for amorphous oxide semiconductor thin-film transistors (AOS TFTs) with higher mobility. A physics-based model for carrier transport in an amorphous semiconductor is...
The objective of the work reported herein is to explore the impact of decreasing channel thickness on radio-frequency (RF) sputtered amorphous indium-gallium-zinc oxide (a-IGZO) thin-film transistors (TFTs) electrical performance through the evaluation of drain current versus gate voltage (I[subscript D] − V[subscript G]) transfer curves. For a fixed set of...
In this dissertation, I qualitatively examined the meaning of mothering a child with autism in two countries: the United States and South Korea. The overarching research question focused on how sociocultural ideas about mothering and disability, particularly autism spectrum disorders, shape women’s understanding of themselves and their children with disabilities....
Resistive random access memory (RRAM) is a non-volatile memory technology based on resistive switching in a dielectric or semiconductor sandwiched between two different metals. Also known as memristors, these devices are potential candidates for a next-generation replacement for flash memory. In this thesis, bipolar resistive switching is reported for the...
Copper zinc tin sulfide (CZTS) is a potential solar material for thin film solar cells according to its suitable band gap in the visible light range, high absorption coefficient, low toxicity, good photostability and relative earth abundance of component elements. However, the production cost of this solar thin film material...
Peroxiredoxins (Prxs) were not recognized as a family of enzymes until the 1990s but are now known to be the dominant peroxidases in most organisms. Here, the history and fundamental properties of peroxiredoxins are briefly reviewed, with a special focus on describing how an exquisitely tunable balance between fully folded...
The stability of citrate-capped silver nanoparticles (AgNPs) and the embryonic developmental toxicity were evaluated in the fish test water. Serious aggregation of AgNPs was observed in undiluted fish water (DM-100) in which high concentration of ionic salts exist. However, AgNPs were found to be stable for 7 days in DM-10,...
Ample research has demonstrated the largely untapped potential of bioactive peptides (BAPs) for treating systematic chronic inflammation (SCI). Protein hydrolysates are the mixture of peptides resulting from the hydrolytic breakdown of a protein. Numerous hydrolysates contain BAPs and exert beneficial effects in both in vitro and in vivo models. In...
Peroxiredoxins (Prxs) make up an ancient family of enzymes that are the predominant peroxidases for nearly all organisms and play essential roles in reducing hydrogen peroxide, organic hydroperoxides, and peroxynitrite. Even between distantly related organisms, the core protein fold and key catalytic residues related to its cysteine-based catalytic mechanism have...
Siletzia is a basaltic Paleocene and Eocene
large igneous province in coastal Oregon,
Washington, and southern Vancouver Island
that was accreted to North America in the
early Eocene. New U-Pb magmatic, detrital
zircon, and ⁴⁰Ar/³⁹Ar ages constrained by
detailed field mapping, global nannoplankton
zones, and magnetic polarities allow correlation
of...
Full Text:
(Fig. 1). These volcanic complexes
include the Siletz River Volcanics (SRV) of Ore-
gon, the Crescent
Many studies addressing the toxicity of silver nanomaterials have found that smaller sized silver nanoparticles are usually more toxic to organisms and in cell culture than particles of larger sizes yet it is not entirely clear why. We investigated the size dependent toxicity of silver nanoparticles by measuring the response...
New low enriched uranium (LEU) fuels are being developed for replacement of high enriched uranium (HEU) fuels in high power research reactors. U-Mo LEU plate fuels have been identified as a candidate for replacement of current HEU fuels. However, U-Mo fuels tend to exhibit accelerated swelling typically at fission densities...
Authentication protocols play important roles in network security. A variety of authentication protocols ranging from complex public-key cryptosystems to simple password-based authentication schemes have been proposed. However, currently there is no fully secure authentication scheme that can resist all known attacks. When a user authentication is performed over an insecure...
In this article, we provide a brief overview of generative artificial intelligence and large language models. We then propose eight critical questions that libraries should ask when exploring this technology and its implications for their communities. We argue that libraries have a unique role in facilitating informed and responsible use...
The differentiation of precursor cells into mature adipocytes (adipogenesis) has been an area of increased focus, spurred by a rise in obesity rates. Though our understanding of adipogenesis and its regulation at the cellular level is growing, many questions remain, especially regarding the regulation of the metabolome. The 3T3-L1 cell...
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):11566–78. doi: 10.1074/
jbc.M111.259721 PMID: 22298784
11. Lee J, Kim D, Choi J, Choi H, Ryu JH, Jeong
The performance of thin film metal-insulator-metal (MIM) diodes is investigated for a variety of large and small electron affinity insulators using ultrasmooth amorphous metal as the bottom electrode. Nb2O5, Ta2 O5, ZrO2, HfO2, Al2 O3, and SiO2 amorphous insulators are deposited via atomic layer deposition (ALD). Reflection electron energy loss...
This thesis studies cooperative techniques that rely on femtocell user diversity to improve the downlink communication quality of macrocell users. We analytically analyze and evaluate the achievable performance of these techniques in the downlink of Rayleigh fading channels. We provide an approximation of both the bit-error rate (BER) and the...
In this dissertation, the structural properties, thermodynamics and defect behavior of amorphous metal oxides and polyoxometalates are studied. Amorphous metal oxides have many applications, most notably as a semiconducting material used as the active matrix of thin film transistors. Alas, the amorphous nature of these materials makes studying them rather...
Metal-insulator-metal (MIM) tunnel devices have been proposed for high speed applications such as hot electron transistors, IR detectors, optical rectennas for IR energy harvesting, and backplanes for LCDs. The majority of these applications require highly asymmetric and non-linear current versus voltage (I-V) behavior at low applied voltages and ultra-high frequencies....
Novel graphite intercalation compounds (GICs) and associated chemistry have been explored, specifically: (1) containing alkyl- substituted imidazolium cations; (2) a series containing alkaline earth metal (Mg, Ca, Sr, Ba) cations with ethylenediamine (en) co-intercalates; (3) showing reversible intragallery M-M bonding and (4) via electrochemical intercalation of Mg cations with potential...
Significance: Parasite survival and virulence relies on effective defenses against reactive oxygen and nitrogen species produced by the host immune system. Peroxiredoxins (Prxs) are ubiquitous enzymes now thought to be central to such defenses and, as such, have potential value as drug targets and vaccine antigens. Recent Advances: Plasmodial and...
In this dissertation, the process of computational modeling of amorphous oxide materials is studied. Amorphous oxides have random atomic arrangements with no long-range structural order which makes it difficult to study structure-property relationships. Despite the difficulties, amorphous oxides have great uses as semiconductors and dielectrics in thin-film transistors. The ability...
Copper sulfides (Cu[subscript x]S) are compound semiconductor materials that exhibit considerable optical and electrical properties varying significantly as a function of the composition. Copper sulfide thin films can be used in many applications, such as solar control coatings, solar cells, photothermal conversion of solar energy, electroconductive coatings, and microwave shielding...
Investigations on the application of self-assembled monolayers (SAM) to indium gallium zinc oxide (IGZO) thin film transistors (TFT) for fabrication and channel modification are presented. The back channel of IGZO thin film transistors can be modified by the absorption of self-assembled monolayers. The electrical properties of the IGZO exposed back...
Victoria blight, caused by fungus Cochliobolus victoriae, is a disease originally described on oats and recapitulated on Arabidopsis. Victoria blight is used as a model plant disease that conforms to an inverse gene-for-gene interaction. C. victoriae virulence is dependent upon its production of victorin, a host-specific toxin that induces programmed...
Zinc Sulfide (ZnS) thin film, with a wide band gap, has been used for many applications, such as buffer layer for CIGS solar cells, light emitting diodes and thin film electroluminescent devices.
In this work, ZnS thin films were prepared using two different deposition processes. In the first method, ZnS...
Paleomagnetic directions from the Eocene Tillamook Volcanic Series of the Oregon Coast Range
point 460 clockwise from the expected Eocene field direction. Potassium argon dating of six dikes and
flows from this formation yields a mean age of 44.3 ± 0.6 m.y. These results establish that the Oregon
coastal block...
Atherosclerosis is the underlying cause of ischemic heart disease and stroke and is the leading cause of death worldwide, especially in developed countries. As an inflammatory disease of arteries in a hyperlipidemic milieu, expression of adhesion molecules, such as endothelial-leukocyte adhesion molecule-1 (E-selectin) and intercellular adhesion molecule-1 (ICAM-1), on endothelial...
Hazelnuts are commonly consumed raw and are valued for their numerous health benefits and antioxidant properties. Increased foodborne illness outbreaks associated with Salmonella and Escherichia coli O157:H7 contamination of tree nuts and peanuts generate a need for improving agricultural sanitation procedures. Food-safe chemical sanitizers have shown promise for reducing pathogenic...
Interest in nanomaterials is motivated partly by their potential for sensor arrays to detect
different gases. Nanowires in particular are of interest because their high surface-to-volume
ratio promises the possibility of high sensitivity. However, because of their discrete
quasi-one-dimensional geometry, electrical integration of nanowires into photolithographically
defined devices and circuits...
The electrical stability of amorphous indium-gallium-zinc oxide (a-IGZO) thinfilmtransistors (TFTs) is investigated for flat-panel display applications. Althoughproducts incorporating a-IGZO TFT backplanes are already commercially available,e.g., iMac with 5K retina display, technical challenges need to be addressed for nextgenerationapplications, e.g., active-matrix organic light-emitting diode displays.Device stability is one crucial issue. The...
The focus of this thesis is the investigation of thin-film transistors (TFTs) based on amorphous oxide semiconductors (AOSs) in two circuit applications. To date, circuits implemented with AOS-based TFTs have been primarily enhancement-enhancement inverters, ring oscillators based on these inverters operating at peak frequencies up to ~400 kHz, and two-transistor...
In Intense Pulsed Light (IPL) sintering, pulsed large-area visible light from a xenon lamp is absorbed by nanoparticle films or patterns and converted to heat, resulting in rapid sintering of the nanoparticles. This work experimentally characterizes IPL sintering of silver nanoparticle films. A newly observed turning point in the evolution...
The action of pendant, polyethylene oxide (PEO) brush layers as nonfouling coatings for
biomedical materials is well understood. However progress toward clinical application of stable, high density PEO coatings has historically been impeded by the lack of cost effective, noninvasive methods for their preparation. Triblock polymers featuring a hydrophobic, polypropylene...
Fabrication techniques and process integration considerations for amorphous oxide semiconductor (AOS) thin-film transistors (TFTs) constitute the central theme of this dissertation. Within this theme three primary areas of focus are pursued.
The first focus involves formulating a general framework for assessing passivation. Avoiding formation of an undesirable backside accumulation layer...
Seep characteristics at different geologic settings are the subject of this review primarily based on results of the Research Consortium SFB 574. Criteria are drawn from examples on the erosive convergent margin off Costa Rica, the accretionary margin off Chile supplemented by examples from the transform margin of the Golf...
The optical and electronic properties of amorphous oxide thin films depend crucially on chemical composition, and deposition process variations which give rise to sub-gap defect states. Consequently, there is a need for a reliable, high-throughput method to extract sub-gap defect densities of states in amorphous oxide thin films. We present...
Cutaneous melanoma remains the deadliest form of skin cancer, with a
diagnosis of metastasis indicating a median survival rate of less than a year. Solar ultraviolet (UV) radiation, especially childhood sun exposure, is an important etiological risk factor of melanoma. Previous studies determined that mice selectively lacking the nuclear hormone...
Histone deacetylase (HDAC) inhibitors have the potential to de-repress epigenetically silenced genes in cancer cells, leading to cell cycle arrest and apoptosis. Dietary HDAC inhibitors derived from natural phytochemicals are promising anticancer agents. In this thesis, metabolites from natural organosulfur and organoselenium compounds, i.e. allyl mercaptan (AM), β-methylselenopyruvate (MSP) and...
A unique microreactor-assisted nanomaterial synthesis and printing process was studied for the fabrication of patterned metal oxide nanostructured thin films. The process uses a continuous flow microreactor to control and generate a reactive chemical flux that was transported to a patterned microfluidic channel. The microreactor-assisted nanomaterial synthesis process can generate...
Vibrio parahaemolyticus, a naturally occurring halophilic pathogen, is seasonally abundant in marine and estuarine environments. It is also the leading cause of gastroenteritis in humans world-wide. Numerous outbreak incidences associated with the pathogenic Vibrio parahaemolyticus contaminations in oyster products have raised public-health concerns as well as economic challenges to the...
The environmental health science community recognizes polycyclic aromatic hydrocarbons (PAHs) as a re-emerging class of environmental pollutants due to their persistence and prominence in mixtures of concern. Due to their widespread distribution in the environment, exposure to PAHs often occur as complex chemical mixtures. Exposures are linked to numerous adverse...
Nanomaterials are expected to enable significant advances in several technological fields in coming years. Among them, electronics has emerged as one of the most likely benefactors from the ability to control matter on the nanometer-scale. For many electronic devices synthesized nanomaterials must be integrated into thin film structures. Vapor-based deposition...
High-potential molecules derived from biomass sources may suitably replace or supplement traditional nonrenewable hydrocarbon fuels to reduce pollution and fuel processing costs. Due to expensive and time-consuming property testing, models that predict key properties from optical data would initially vet potential additives before investment and bench-scale testing. Attenuated Total Reflection...
Shoulder injuries, especially those caused by rotator cuff tears, are a pervasive problem in human and canine patients. The ability to quickly and accurately diagnose rotator cuff tears is important for early and targeted treatment. Prior clinical work has demonstrated that ultrasound and magnetic resonance imaging effectively diagnose these tears....
CuInGaSe₂ (CIGS), a promising thin film solar cell material, has gained lots of
attention in decades due to its high energy conversion efficiency and potential lower
manufacture cost over conventional Si solar cells. As a cheaper processing method
compared to vacuum-based techniques, solution-based deposition has been
successfully applied to fabricate...
ZnO nanowires (NWs) are good candidates for chemical sensing because of their high surface-to-volume ratio. In this work, ZnO nanobridge sensors were fabricated utilizing a novel method which uses carbonized photoresist (C-PR) as a nucleation layer. The use of C-PR allows simultaneous growth and integration of NWs to lithographically-defined features....
Predicting the net effects on the carbon and water
balance of semi-arid forests under future conditions depends
on ecosystem processes responding to changes in
soil and atmospheric drought. Here we apply a combination
of field observations and soil–plant–atmosphere modeling
(SPA) to study carbon and water dynamics in a regenerating
ponderosa...
Melanocytes are dendritic, pigment-producing cells located in the skin and are responsible for its protection against the deleterious effects of solar ultraviolet radiation (UVR), which include DNA damage and elevated reactive oxygen species (ROS). They do so by synthesizing photoprotective melanin pigments and distributing them to adjacent skin cells (e.g.,...
This work investigates the effect of cation substitution on the properties of the lead-free, solid solution (Na₀.₅Bi₀.₅)TiO₃-BaTiO₃ (NBT-BT). Substitution into NBT-BT increases disorder and increases the relaxor ferroelectric properties. These relaxor ferroelectric materials show large piezoelectric strains that can be utilized in actuator applications. Ceramic samples were prepared using standard...
The production of fuel ethanol from lignocellulosic biomass has the potential to replace a significant portion of non-renewable transport fuels. Woody feedstocks are composed of cellulose, hemicellulose, and lignin. Glucose, the monomer of cellulose, is readily utilized by wild-type S. cerevisiae, but xylose, which comprises 60% of the sugar in...
One post-transcriptional mechanism that regulates the progression of cancer and other diseases involves small 22-23 nucleotide sequences called microRNA (miR). Early detection of small changes in concentration of these biomarkers holds potential to diagnose diseases at their earliest stages. Use of current nucleic-acid based biosensors, like molecular beacons, for in...
Severe droughts occurred in the western United States during recent decades, and continued human greenhouse gas emissions are expected to exacerbate warming and drying in this region. We investigated the role of water availability in shaping forest carbon cycling and morphological traits in the eastern Cascade Mountains, Oregon, focusing on...
Milk is the first source of nutrition for all mammalian neonates. The complex matrix that constitutes milk has evolved to provide optimal nutrition for the newborn, for each species, respectively. Milk fat, originating in mammary epithelial, forms lipid droplets which are stabilized in the aqueous environment by bioactive polar lipids...
The objective of this research is to support DfX considerations in the early phases of design, particularly Design for the Environment. In order to include DfX considerations, especially early in the design process, there needs to be access to knowledge and information that is usually only applicable further downstream in...
Severe droughts occurred in the western United States during recent decades, and continued human greenhouse gas emissions are expected to exacerbate warming and drying in this region. We investigated the role of water availability in shaping forest carbon cycling and morphological traits in the eastern Cascade Mountains, Oregon, focusing on...
Ocean Drilling Program (ODP) Leg 204 to Hydrate Ridge, located on the continental slope offshore Oregon (USA), was the first drilling expedition dedicated to understanding gas hydrate processes in accretionary complexes and provided a testbed for a number of different techniques for estimating the gas hydrate content of sediments. It...
There is a growing need for individualized instructional designs in 4-year institutions due to: 1) growing undergraduate enrollment trends across the U.S., 2) broader diversity in students backgrounds, and 3) the growing prevalence of asynchronous remote learning. With the growth in computer technology in education, tools such as adaptive intelligent...
While the role of ubiquitin in protein degradation is well established, the role of other ubiquitin-like proteins (UBLs) in protein degradation is less clear. Neural precursor cell expressed developmentally down-regulated protein 8 (NEDD8) is the UBL with the highest level of amino acid identity when compared to ubiquitin. Here we...
The effect of cosputtered catalyst on growth and alignment of carbon nanotubes (CNTs) grown by plasma enhanced chemical vapor deposition (PECVD) was investigated. Aligned CNTs were observed using a cosputtered catalytic metal deposited directly on boro-aluminosilicate glass. Catalytic metal alloys were sputtered directly onto the substrate using magnetron sputtering. Deposition...
Peroxiredoxin (Prx) enzymes catalyze the reduction of hydrogen peroxide, peroxynitrous acid, and organic peroxides, and are extremely efficient peroxidases, with k[subscript cat]/K[subscript M] on the order of 10⁷ - 10⁸ M⁻¹ s⁻¹. Besides their role in oxidative stress defense, evidence has accumulated that some eukaryotes, including humans, use Prxs as...
This work investigates the relationship between the local structure and physical properties of a set of classical (MgTiO3, CaTiO3, SrTiO3, and BaTiO3) and complex ((1-x)Ba(Zr0.2Ti0.8)O3-x(Ba0.7Ca0.3)TiO3[BZT-BCT], Na0.5Bi0.5TiO3 [NBT]) perovskite electroceramics. The materials in this work were synthesized via standard solid state ceramic synthesis, the structure was investigated through a number of...
Indium-gallium-zinc oxide (IGZO) and zinc-tin oxide (ZTO) are investigated for thin-film transistor (TFT) applications. Negative bias illumination stress (NBIS) is employed for electrical stability assessment. Unpassivated IGZO and ZTO TFTs suffer from severe NBIS instabilities. Zinc-tin-silicon oxide is found to be an effective passivation layer for IGZO and ZTO TFTs,...
Porous carbon is indispensable in modern technology applications. It is used for energy storage, gas separation, water purification, catalyst support, and chromatography. The diversity of its applications stems from its unique properties, including high specific surface area, tunable pore volume, and chemical stability. Specifically, the large surface area provides high...
Since their discovery in the 1990s, the great potential of carbon nanotubes (CNTs) has made them a focus of many research endeavors, including their application as components of biosensors. The inherent chemical "inertness" of CNTs makes their application to biosensing a challenge. It is necessary to "decorate" their surfaces to...
The purpose of this research was to develop tools and germplasm for the production of tomatoes (Solanum lycopersicum L.) with high fruit phenolics without the use of genetic engineering. A candidate gene analysis was undertaken to identify genes regulating anthocyanin biosynthesis in tomato fruit (Aft, Abg, atv, and Purple Smudge)....
Oxides are a versatile class of materials with a wide range of electronic, optical, and magnetic properties. This makes them ideal for use in a multitude of functional devices for oxide electronics, electrochemical conversion, and storage. The overall performance of these devices is governed by atomic scale charge and mass...
We have developed a compact micro total analysis system (μTAS) to serve as a platform for in-situ spectrophotometric water quality monitoring. Individual fluidic, optical, and electrical components were designed, developed, and characterized. These components were combined in both an integrated (single lithographic “chip-based” platform) and a modular manner. The microfluidic...
Peroxiredoxins (Prxs) are dominant peroxide-reducing enzymes with two important roles: they protect all organisms from oxidative damage induced by peroxides, and in eukaryotes, they participate in hydrogen peroxide signaling pathways. This dissertation presents studies aimed at the biophysical characterization of select Prxs and a Prx reductase to elucidate their structure-function...
Tan spot of wheat is an economically significant disease caused by the fungal pathogen, Pyrenophora tritici-repentis. Certain races of the fungus secrete Ptr ToxA (ToxA), a 13.2 kDa proteinaceous host-selective toxin that is responsible and sufficient to cause disease in susceptible wheat varieties. Disease symptoms develop only when the ToxA...
Solid-state amorphous materials show amazing promise in thin-film electronics. The interface-to-bulk ratio of thin films makes interfacial chemistries of these systems of utmost importance. Thin films of amorphous metals, dielectrics and semiconductors have novel chemistries that are not only based upon their elemental constituent makeup, but also based upon the...
Grapes (e.g. Vitis vinifera L.) are one of the more important fruit crops from an economic standpoint with world market values over 550 million US dollars in 2007 and 2008, second to apples (United States Department of Agriculture). While a satisfactory level of ripeness is of primary concern, the quality...
This dissertation is separated into two parts according to the two major distinct research projects. In Part I, the full account of synthetic studies toward C10-functionalized lycopodium alkaloids is described. In Part II, the detailed discussion on the exploration of the Pummerer cyclization methodology and its application to the total...
Atmospheric pressure plasma is non-thermal at millimeter to micrometer separations. It represents an alternative low exergy initiator of many chemical reactions. In many instances heat, light or sound are not efficient providers of the necessary energy to overcome chemical activation barriers. The focus of this research is applying dc nonthermal...
Vibrio bacteria are commonly found in freshwater, marine, and estuarine environments. Members of this genus can exist in commensal relationships with marine animals or as planktonic bacteria, however, they are well known for their roles as pathogens towards humans and animals. In this dissertation, I investigated aspects of host-bacteria relationships...
Silicon carbide (SiC) and aluminum nitride (AlN) exhibit a combination of thermal and mechanical properties that are relevant to applications in electronics, aerospace, defense and automotive industries. However, the successful translation of these properties into final applications lies in the net-shaping of these ceramics into fully dense microstructures. Increasing the...
Hop (Humulus lupulus L. var. lupulus) is a diploid, dioecious plant with an extensive history of cultivation and use in brewing, as a textile, and for its therapeutic properties. Hop is prized for its ability to produce a variety of aromatic and flavor compounds, as well as compounds with anti-microbial...
Cryptographic obfuscation is a powerful tool that makes programs “unintelligible” yet still runnable. It essentially gives programs the ability to keep secrets. The practical applications of obfuscation range from keeping secrets in banking applications to preventing software theft to providing secure messaging applications. The cryptographic applications of obfuscation are also...
Seed dormancy is defined as the inability of viable seeds to germinate under conditionsotherwise favorable for germination. Dormancy provides a strategy for seeds to germinateat an appropriate time. Abscisic acid (ABA) is a major hormone involved in the regulationof seed dormancy. To elucidate the molecular mechanisms of dormancy, the twoexperimental...
This dissertation works towards determining the mechanisms driving the Mo isotopic composition of soils, and how these signals may be used to refine the use of Mo as a proxy of biogeochemical processes. The first step towards quantifying Mo fractionation in soils is to determine the mechanisms controlling Mo accumulation,...
The development of technologies such as Building Information Modeling (BIM), light detection and ranging (lidar), and sensor-based systems poses new opportunities for researchers to rethink how construction safety and health can be approached during the design, planning, and construction phases of a project. Nevertheless, the majority of the technology applications...
Biological hydrogen production from renewable feedstocks was reckoned as a promising method for sustainable energy production. Bioelectrochemical hydrogen production using microbial electrolysis cells (MECs) demonstrated superiorities over the conventional methods for hydrogen production. The introduction of the membrane-less single chamber design further improved the feasibility of MECs for practical application,...
To become a competitor for fossil fuels such as coal, solar installations will need to be produced and installed at a price equal to or below grid parity. This price can be approached by either reducing the overall system cost or increasing system efficiency. The focus of this paper is...
This study considered regional forest policies for sequestering carbon in existing
forests in western Oregon. A model of log markets in western Oregon was employed to
examine the impacts of forest policy changes on future carbon stock, harvests, and
management activities. A carbon tax program, as a mitigation option for...