Microbial electrochemical systems (MESs) have attracted much research attention in recent years due to their promising applications in renewable energy generation, bioremediation, and wastewater treatment. In a MES, microorganisms interact with electrodes via electrons, catalyzing oxidation and reduction reactions at the anode and the cathode.
The bacterial community of a...
Shewanella oneidensis MR-1 is a gram-negative, facultative anaerobic bacteria with the capability of dissimilatory metal reduction. The ability of the organism to reduce a wide range of solid metal-oxides during anaerobic respiration makes it an ideal candidate for the powering of microbial fuel cells (MFCs), which capture the electrons discharged...
Developing new wastewater treatment technologies which will off-set the high-energy cost associated with treatment is necessary to maintain both water and energy security. Microbial fuel cell technology represents one such option. However, there are still many obstacles to overcome before practical application of this technology can be realized. Improving cathode...
While water scarcity and energy demand are continuously increasing in the world, alternative sources are needed to meet the requirement of a growing population. Microbial Fuel Cell (MFC) is a sustainable technology that converts organic matter in wastewater into electricity, thus it can be a potential alternative source for water...
A benthic microbial fuel cell (BMFC) is an electrochemical device that
generates current from the redox gradient at the sediment-water interface. Early
prototypes had anodes buried in anoxic sediments and cathodes in overlying water.
The BMFCs described in this dissertation are based on a chamber design that enables
the use...
Microbial electrolysis provides a new approach for hydrogen generation from renewable biomass. At current stage, the most likely limiting factors for successful scale up of this technology are the large internal resistance and high fabrication cost. This dissertation presents an attempt to overcome these limitations by investigating novel microbial electrolysis...
Further enhancement of energy generation is desired for practical application of anaerobic microbial systems such as microbial fuel cells (MFC) and anaerobic digesters (AD). A possible approach is to enhance the ability of microbial communities to transfer electron extracellularly in the form of electrical current. Critical to perform direct extracellular...
Photobiological hydrogen production -- the use of photosynthesis to split water into hydrogen and oxygen -- presents an opportunity for efficient and large-scale solar biofuel development. One of the major challenges in this area is competition for reductant between the hydrogen-evolving hydrogenase enzyme and other metabolic pathways. In this work...
The thesis documents research about combining the National Pollutant Discharge Elimination System (NPDES) Permit Program with the Impact 2002+ methodology to conduct a Life Cycle Assessment (LCA) for wastewater treatment processes. The LCA for the operational phase of a local wastewater treatment plant was performed and the environmental impacts caused...
The graphite anode reaction in a fused carbonate electrolyte is
studied theoretically and experimentally. Data on open circuit cell
potentials indicate, for operation below 900°C, only a small fraction
of the free energy of reaction is converted to electrical work.
Anode polarization measurements were made for current densities
of up...
The mechanism of continuously chlorinated silver-silver
chloride electrode performance was studied by using a wiped, rotating,
partially submerged, cylindrical silver cathode. The cell
performance using a zinc anode was measured, and the rate of
chlorination of silver was calculated for several water saturated
chlorine atmospheres.
At 75°F, with a chlorine...
A Mixed Reactant Single Chamber (MRSC) Fuel Cell is a relatively recent concept in the field of fuel cell engineering originally developed in the late 1950’s. Typical fuel cells have separated reactants (a separated fuel and oxidizer) that react on their usually non-selective electro-catalytic materials. A mixed reactant fuel cell...
Anoxic sediment overlain by oxic seawater establishes a voltage gradient on the order of 0.7-0.8V across the sediment-water interface. This study follows Reimers et al. (2001) and Tender et al. (2002) who reported the development of a seafloor fuel cell to harvest electrical energy from this potential difference. Prototype fuel...
Pacific Northwest Generating Cooperative (PNGC) operates the Landfill Gas to
Energy Facility at Coffin Butte Landfill in Corvallis, OR. At this facility, three internal
combustion engines use the landfill gas (predominantly methane and carbon dioxide) as
fuel to turn generators that produce enough electricity to power 1,800 average sized
homes....
A techno-economic analysis (TEA) was performed to evaluate the technology, cost, and resource use for algal biofuel production based on today’s economics and technology. The basic goal of this study is to develop a model to calculate the mass and energy balances and costs to produce 10 million gal of...
Polymer electrolyte membrane (PEM) fuel cells are being studied for use as high efficiency power plants in alternative fuel vehicles. To maintain high efficiency the operating temperatures of the membranes in these fuel cells must be closely monitored and controlled. However, the environment inside of the fuel cell is not...
Radiation health and safety issues associated with a plutonium-powered radioisotope
powered micro fuel cell (RMFC) were evaluated. The RMFC converts water into its
component elements by radiolysis and the resultant hydrogen is used to power the fuel
cell. This device is under development and is being considered for possible
deployment...
Direct red Solid Oxide Fuel Cell (SOFC) Turbine hybrid plants have the potential to dramatically increase power plant efficiency, decrease emissions, and provide fast response to transient loads. The US Department of Energy's (DOE) Hybrid Performance Project is an experimental hybrid SOFC plant, built at the National
Energy Technology Laboratory...
To improve the performance of solid oxide fuel cells, a secondary power cycle can be driven by the recuperation of exhaust gas heat. Microchannel recuperators are attractive for waste heat recuperation due to compact form factors which also minimize the mass of the expensive superalloys required. This paper introduces a...