A field study on grass field burning was conducted in the
Willamette Valley of Oregon during the summer of 1965. Approximately 243,000 acres of grass fields are burned in the valley during
August and September. Serious air pollution problems result from
this burning. The purposes of the study were to...
A study was conducted to determine what effects the type of
pollutants, storage conditions, storage time, and method of sample
conditioning have on the reported weight of an air pollutant collected
by filtration. Samples were collected from a refuse dump, an arc
furnace smelting nickel ore, and a rotary kiln...
Submicron particulate (mean size of 0.52 microns) was filtered
from air at substantially atmospheric temperature and pressure by
passing air up through a bed of fluidized glass shot in a two inch column.
Removal efficiency, defined as the percentage removal of
particulate from the air stream, was essentially constant during...
The "Teepee" type wood residue incinerator, similar to
many other sources, requires sampling at the point where the emissions enter the atmosphere. Because the location of the emission
point is hazardous and unpleasant for the operation of a sampling
probe, a portable, tilt-up column was developed which permitted installation, operation,...
The respiratory tract is lined with a mucous blanket which is
motivated by a ciliated epithelium. This blanket includes a lower
serous layer of fluid through which the cilia beat and an upper viscid
layer into which particulates from the inhaled air are deposited.
The movement of the mucous blanket...
A source test was conducted to determine the particulate and the
total gaseous hydrocarbon emissions from a gas heated veneer dryer.
Samples were taken on eight separate days from the exhaust stacks
while the dryer was processing Douglas fir veneer. Of the eight days,
three was used to determine the...
An integrating nephelometer was set up at the Eugene Airport
which is located five miles north of Eugene, Oregon, on Highway
99 West. Continuous atmospheric scattering coefficient readings
were obtained from July 1, 1969, to August 28, 1969. These data
are converted to meteorological range through the use of the...
The removal of ozone from an air stream by activated-cocoanut
charcoal was investigated from the literature and experimentally.
The experimental investigation showed that activated-cocoanut charcoal
can be used to remove concentrations of ozone less than 1.0
ppm with high efficiencies. The mechanism of the ozone removal
appeared to be a...
Many agricultural fields are burned in the Willamette Valley
of Oregon during the summer for economic reasons. A major air
pollution problem results from these burnings. The purpose of this
study was to develop relations between the maximum plume height
and some of the independent variables affecting this plume height,...
Ammonium chloride aerosols of submicron size generated by
condensation and dispersion methods were treated, shortly after aerosol
charging, with shock waves originating from diaphragm pressure
ratios of up to 5.75.
The fraction of the particulate matter remaining in suspension
after a given time was measured as an indication of coagulation...
An emmission sampling system was developed to measure pollutants
emitted from a mobile agricultural incinerator developed at
Oregon State University. The system was designed to collect a particulate
sample on an 8" x 10" fiber glass filter and collect a gaseous
sample in a plastic bag. Pollutants measured were particulates...
A mathematical model was developed that relates the
ratio, R, of two light flux measurements to the mass concentration,
m, of the atmospheric aerosol particles between
a source of parallel light (e.g., the sun) and the measuring
system. R is defined as the ratio of the light fluxes
passing through...
Emissions of oxides of nitrogen from a small (15 kW) turbine generator burning high fuel bound nitrogen fuels were measured by a chemiluminescence method. Kerosene was used as the base fuel and pyridine was added to achieve different fuel bound nitrogen levels. Mixtures of 0.0%, 0.5%, and 1.0% (by weight)...
This experiment is concerned with sampling submicrometer
particles in near sonic and supersonic flows.
The study employed a high volume condensation aerosol
generator to produce stearic acid particles having a
geometric mean diameter of 0.8 μm and a geometric
standard deviation of 1.28. The aerosol was diluted
with dry air...
A model of an exhaust plume was developed and programmed
on a digital computer. The purpose of the model was to predict the
concentration and size distribution of ice particles produced from
automobile exhaust during arctic conditions. The model accounted
for the nucleation, growth, and freezing of the condensed water...
A high volume sampling system, employing Nuclepore filters and
designed for sampling particulate in the plumes from industrial
sources using a light aircraft, is described. The effluent of kraft
paper mills was sampled using this system and then analyzed by
electron microscopy.
Size distributions of particles were obtained at several...
Part 1
The pyrolysis of cis-1-trimethylsiloxy-1-cyclopr opyl-3-cyclononene in the temperature range 285-350° is described. Instead
of siloxy-Cope rearrangement, undesired desiloxylation took place.
Part 2
Gas-phase pyrolytic rearrangement of 2-phenyl-1-trimethylsiloxy-1-vinylcyclononane was investigated in a static system
in the temperature range 213-330°. It was discovered that
three major products resulted: cis- and...
Both oxy-Cope and siloxy-Cope rearrangements involve
(1, 3) and (3, 3) sigrnatropic shifts. Both the concerted mechanism,
and the stepwise mechanism via a diradical intermediate are possible.
In a cyclic system such as cis-l-vinylcyclooct-3-en-l-ol, the thermal
rearrangement takes place preferably through a diradical intermediate.
At high temperature, the reaction also...
Part I
The pyrolysis of cis- and trans- 1, 2-divinyl-1- trimethylsiloxy -
cyclohexane, II- and III-TMS, under the same conditions as the
pyrolysis of cis-l-vinyl -1-trimethylsiloxycyclooct-3-ene, I-TMS,
confirms that a sequence of concerted reactions for the rearrangement
of II- and III-TMS to trans-l-trimethylsiloxycyclodec-3-ene,
IV-TMS, is a viable pathway in the...
This paper describes the synthesis of t-butyl bicyclo[7.1.0]
decane-2-percarboxylate and its photolytic decomposition. The title
compound was found to undergo simple homolytic cleavage when exposed
to light of 2537 A; producing the cyclodecyl radical, carbon dioxide,
and t-butoxy radical. The largest percentage of products arose from
an intimate radical pair...
The reactions of cyclodeca-1, 2, 5, 8-tetraene with mercuric salts
in solvents of varying nucleophilicity are described. Instead of forming
the usual oxymercuration products reported for reactions of olefins
and allenes with mercuric salts, the major products obtained in the
present cases result from the initial electrophilic addition of the...
The thermolysis of trans-1 -trimethylsiloxy- 1-vinylcyclotridec-
3-ene (VI-OTMS) led to the formation of two major products: 4-vinylcyclotridecanone
(VII) and cyclopentadec-5-en-l-one (VIII) after
hydrolysis. Ketone VII is produced by a concerted [3, 3] sigmatropic
shift, while ketone VIII is formed by a [1, 3] sigmatropic shift with
a concerted or diradical...
The reaction of cyclodeca-1,215triene with mercuric salts
gave only rearranged hydrocarbon, tricyclo[4.4.0.0²'⁴]deca-5ene
in acetic acid. Other catalysts [Rh(CO)₂C1]₂ and AgC10₄ gave
the same rearranged hydrocarbon. The isomerization is proposed
to proceed through a "metalcomplexed" carbenoid intermediate.
The reaction of bicyclo[7.1.0 ]deca-213diene gave
oxymercurated products.
In an attempt to provide a practical means to measure the information
processing capacity of a real-time digital processing system a
theoretical framework, the Real-Time Schemata, whose basis is a
schematic description and a measure of "useful information," is presented.
The description applies to processes that would typically be
implemented...
Pyrolysis of 4-cycloheptene-l-methyl acetate under flow conditions at 285° gives only rearranged bicyclic acetates and hydrocarbons rather than the anticipated simple elimination product methylenecyclohept- 4-ene. These rearranged acetates have the same structures and are formed in virtually the same relative percentages as those observed in the "π- route" solvolysis of...
A procedure for displaying cursory computer analyses of time
series acoustic signals is described. The graphic presentation is
optimized for visual analysis. The results displayed represent time
series signals and/or Power Spectral Density estimates.
Both hardware and software components of the procedure are
described and compared with current methods. Suggestions...
The purpose of this study was to determine if the preferences in
clothing fabrics and preferences in home furnishing fabrics are
similar or different in color, design size, and line. The
relationships of age, education, and training in color and design to
agreement of clothing fabrics and home furnishing fabrics...
The potassium salts of certain 1-vinylcycloalk-3-en-l-ols have
been found to undergo sigmatropic ring expansion rearrangements in
HMPA. Preliminary investigations of several benzo-substituted medium
ring systems were undertaken in order to determine which of these
was best suited for further study. A synthetic sequence leading to
the formation of 5-methy1-6-viny1-7,8,9,10-tetrahydro-6-benzocyclo-octenol,
which...
The (±) 8,9:13,14-diseco-norestradiol, a large ring hormone
analog, and its related derivatives, were prepared by a ring expansion
approach. The key step of this approach is the establishment of the
benzocyclododecenone system via the Caubere reaction. This step
not only provides a favorable ring size, it also sets the necessary...
The thermal and anionic rearrangements of substituted 1-vinyltrans-
cyclotridec-3-en-l-ol compounds have been studied to determine
what effects substituents would have on the sigmatropic shift when
placed on the two positions of the 1-vinyl group.
For the thermal rearrangements, the a-substituted vinyl-trans-cyclotridecenols
gave both the [3,3] and [1,3] shift products of...
The potassium salts of a series of 1-vinylcycloalk-3-en-l-ols were found to undergo ring expanding [1, 3]-sigmatropic shifts at 25° when dissolved in hexamethylphosphoramide (HMPA) or 1, 2-dimethoxyethane (DME) with 18-crown-6. The yields and reaction rates were compared with those of the corresponding Siloxy-Cope ring expansions. These anionic cases showed about...
Geophysical surveys in the Gulf of California provided
the data to construct contour maps of bathymetry, free-air
anomalies and total field magnetic anomalies for the area
north of 27° N. Major faults such as the Ballenas-
Salsipuedes, Tiburón, Guaymas, and the South Cerro Prieto
are clearly observable on these maps....
During the summer and fall of 1982, personnel from the Geophysics
Group in the School of Oceanography at Oregon State University conducted
an aeromagnetic survey in the northern Oregon Cascades to
assess geothermal potential and study the thermal evolution of the
Cascade volcanic arc.
Total field and low-pass filtered magnetic...
To assist in the assessment of the geothermal potential of north-central
California and to aid in defining the geologic transitions
between the physiographic provinces of the Klamath Range, the Cascade
Range, the Modoc Plateau, the Great Valley, and the Sierra Nevada
Range, personnel from the Geophysics Group in the College...
Marine geophysical data from the continental margin of Baja
California and the Gulf of California, and geological and geophysical
data from the Baja California Peninsula and mainland Mexico, outline
the major geologic and tectonic features of the Baja California
Peninsula and the surrounding areas from 24.5° N. Lat. to 27.5°...
Gravity, magnetic and seismic data indicate that the oceanic
crust is 9.7 km thick west of the Continental Borderland. The top
of the mantle is about 12 km deep under the Borderland, and deepens
to 27 km beneath the Peninsular Ranges of Baja California. The
mantle is about 20 km...
Gravity measurements made during 1979 and 1980, combined with
existing gravity measurements, provide data for the interpretation
of upper crustal structures relevant to the assessment of the geothermal
potential of south-central Oregon.
West of Upper Klamath Lake, free-air gravity anomalies trend
north-south and average near 35 mgals. East of Upper...
Gravity and magnetic data from cruises by the R/V Yaquina in 1973
and the R/V Wecoma in 1975 provide new data that make possible the construction of a map of the free-air gravity anomalies at sea and simple
Bouguer anomalies on lano in Panama, western Colombia, and the eastern
Panama...
Using gravity, magnetic, bathymetric and seismic
refraction data, I have constructed a geophysical cross-section
of the central part of the northern Gulf of California. The
section exhibits a crustal thickness of 18 km and features an
anomalous block of high density lower basement (3.15 g/cm³)
which probably resulted from rifting...
Gravity and seismic data obtained by the geophysical group at
Oregon State University on the R/V YAQUINA during 1969, 1971, and
1973 plus other available data over the area just west of Nicaragua
and Costa Rica indicate the tectonic complexity of the region. Gravity
measurements show negative free-air anomalies over...