Vanadium pentoxide electrodes were prepared by melting
the powdered oxide around a platinum foil in a pyrex tube. The
electrode was discharged, and the discharge product was studied,
but not identified, by means of chemical and x-ray diffraction analysis.
A study was made of the relationship between the electrode
potential...
A survey of the methods of purification of KC1, for use in
preparing single crystals by growth from the melt, was made. Two
methods, fractional recrystallization and ion exchange, were used.
The purity of the salt and crystals grown from the same salt were
compared with the findings of other...
The dc conductivity of single crystals of vanadium pentoxide
was measured in the three crystallographic directions. The temperature
range examined was -165°C to +25°C. The activation energy
of the conduction process was isotropic and found to be .56 ev. The
conductivity was anisotropic.
Measurements of the Hall effect were attempted...
When the dc conductivities of various pure KC1 crystals were
compared it was found that crystals grown under an HC1 atmosphere,
from salt purified by ion exchange, exhibited lower knee temperatures
than any of the crystals studied. These knee temperatures
were found to be approximately 350°C. From this the total...
The photochemical reaction between O⁻ ions and F centers
was investigated. The activation energy was determined by the
Arrhenius law to be 0.10 + 0.04 eV for temperature below 180°K.
The diffusion of alpha centers towards the oxide ion was eliminated
as the rate limiting step and the low trapping...
The incorporation of europium and dysprosium in potassium
chloride crystals was investigated. The crystals were prepared by
the Kyropoulos method from melts containing the rare-earth chlorides.
The concentration of these rare-earth ions in the crystals was determined
by neutron-activation analysis. The distribution coefficient of
europium and dysprosium between the molten...
Vanadium pentoxide single crystals were grown from the melt.
These crystals were made the cathode in an electrolytic cell and the
polarization and recovery of the electrode were studied under a
variety of experimental conditions.
A study of the electrode potential versus that of the standard
hydrogen electrode as a...
Direct current conductivity measurements on KC1:O[superscript]= crystals
were used to determine an enthalpy of 0.42 ev for the dissociation for
anion-vacancy-oxide ion complex.
The entropy of dissociation was
found to be approximately -4x 10⁻⁴ev deg⁻¹. The intrinsic "activation" energy was found to be 1.91 ev as compared to 1.95 ev,...
The hydroxide ion as a substitutional defect in KC1 can be photo-dissociated
at liquid nitrogen temperature by ultraviolet light. The
photochemistry of this system was investigated by EPR and optical absorption
methods. Theoretical calculations were also performed in an
investigation of the KC1:OH system.
The bleaching behavior of photochemically colored...
Escalating demand for organic blueberries has driven a significant expansion of northern highbush blueberry (NHB; Vaccinium corymbosum L.) production area. This expansion is particularly pronounced in regions of the Pacific Northwest where native soil conditions are sub-optimal for NHB, notably east of the Cascade Mountain Range of Oregon and Washington,...
Organically certified Northern Highbush Blueberry (NHB; Vaccinium corymbosum L.) production in the Columbia Basin region of Oregon and Washington is expanding. Soils in the region are typically calcareous and highly alkaline, often requiring pH adjustment to an ideal range of 4.5–5.5 to support the establishment of the acid-loving, ericaceous crop....
The dielectric relaxation of V₂ 0₅ was investigated using the method of Davidson and Cole. By means of an Argand diagram, deviation from an exact Debye dielectric was established. This was done with the parameter β. For a Debye dielectric β= 1. The largest value of β for V₂O₅ was...
This study was undertaken to determine if strontium chloride could be used to create a trans-generational otolith mark in steelhead (Oncorhynchus mykiss). I completed two strontium injection trials and a survey of juvenile steelhead from various steelhead hatcheries. The two trials measured Sr:Ca ratios in otoliths in response to injections...