Observations of temperature, winds, and atmospheric trace gases suggest that the transition from troposphere to stratosphere occurs in a layer, rather than at a sharp ‘‘tropopause.’’ In the tropics, this layer is often called the ‘‘tropical tropopause layer’’ (TTL). We present an overview of observations in the TTL and discuss...
Observations of water vapor with high temporal and spatial resolution and good horizontal coverage just above the tropical tropopause have been scarce, but a preliminary version of such data has been developed using radiance measurements of the Microwave Limb Sounder. These data reveal distinct variations with periods in the ranges...
We show the signature of the tropical intraseasonal oscillation (TIO) in upper tropospheric moisture and dynamical fields, roughly between 200 and 100 hPa. Relationships among these fields are examined using lag-correlation analysis and using multivariate extended empirical orthogonal functions (MEEOFs), which maximize the shared explained variance among several fields for...
Air passing upward through the tropical tropopause is “marked” by an annually varying water vapor mixing ratio much as a tape recorder marks a magnetic tape; as the air ascends in the tropical stratosphere, these marks are effaced by a combination of vertical diffusion within the tropics and dilution of...
Kelvin-Helmholtz (KH) instability, characterized by the distinctive finite-amplitude billows it generates, is an important mechanism in the development of turbulence in the stratified interior of the ocean. In particular, it is often assumed that the onset of turbulence in internal waves begins in this way. Clear recognition of the importance...
Bromoalkoxylation of dihydropyran with bromine and 1-borneol, followed by dehydrobromination and epoxidation, afforded trans-2-1- bornyloxy-3,4-epoxytetrahydropyran as a major product. This was treated with sodium phenylselenide to give a 1:1 mixture of (2R,3R,4R)- 2-1-bornyloxy-3-hydroxy-4-phenylselenotetrahydropyran and its (2S,3S, 4S) diastereomer. Elimination of the selenoxide, derived from oxidation of the former with hydrogen...