Solid solutions based on the perovskite ferroelectrics Bi₀.₅Na₀.₅TiO₃ (BNT) and Bi₀.₅K₀.₅TiO₃ (BKT) might someday replace current Pb-based ferroelectric and piezoelectric devices. This is one goal of the Restrictions on Hazardous Substances (RoHS) guidelines seeking to limit Pb in consumer devices. Although the Bi-based ferroelectrics are well suited to the task...
Pb(Zr,Ti)O₃ (PZT) is a very attractive material for use in piezoelectric-based microelectromechanical systems (MEMS) due to its high piezoelectric coefficients and ability for large displacements with relatively low applied fields (as compared to electrostatic-based MEMS). The piezoelectric effect is strongly anisotropic, thus it is very desirable to control the crystallographic...
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BradyJ. Gibbons
Abstract:
Pb(Zr,Ti)O3 (PZT) is a very attractive material for use in
Metal-organic frameworks (MOFs) represent an exciting, new class of porous materials. Their hybrid organic-inorganic structure opens up near infinite possibilities to tune and design their structure for specific properties and applications. A new generation of flexible MOFs, following a generation of stiff MOFs, has created additional design space and complexity....
Since bulk p-CuO/n-ZnO heterocontacts were first proposed for gas detection, rapid development has taken place in improving the overall functionality of these structures. While bulk heterocontacts have been shown to exhibit desirable sensitivity and selectivity characteristics, these devices suffer from innate diffusion and ZnO/CuO connectivity drawbacks that limit their effective...
Pulsed laser deposition was used to create 0.1-Bi(Zn₀.₅ Ti₀.₅)O₃-0.9-BaTiO₃ (BZT-BT) thin films to examine the effects of laser energy (2.25 or 2.5 J/cm²) , pulse frequency (2 Hz or 5 Hz), and deposition temperature (550, 600, 650, and 700°C) on the electrical properties of the films. These effects were analyzed...
This work explores the electric field induced strain mechanisms in environmentally benign Bi0.5Na0.5TiO3 (BNT) based piezoelectric thin films. Although BNT-based materials show promise as replacements for toxic Pb-based piezoelectrics, the displacement mechanisms are not consistent between thin films and bulk materials, and the differences have yet to be well understood....
The ternary system (Bi₀.₅Na₀.₅)TiO₃-(Bi₀.₅K₀.₅)TiO₃-Bi(Mg₀.₅Ti₀.₅)O₃ (BNT-BKT-BMgT) was explored along the [75-(x 2) ]Bi₀.₅Na₀.₅TiO₃ - [25-(x 2)]Bi₀.₅K₀.₅TiO₃ - [x]Bi(Mg₀.₅Ti₀.₅)O₃ composition line. Thin films were fabricated using chelated mixing route solutions spin cast onto platinized silicon substrates. Processing parameters such as: excess cation molar%, solution molality, and crystallization temperatures, for composition where x=0,...
Piezoelectric materials convert mechanical strain into a dielectric displacement, as well as the converse, allowing these materials to be used as sensors, actuators, and transducers. Currently, lead zirconate titanate (PZT) is the primary material used in these applications. Due to environmental toxicity and safety concerns associated with Pb, development of...
Lead zirconate titanate (PZT) is well known to exhibit some of the strongest piezoelectric responses, explaining why it is at the heart of piezoelectric-based microelectromechanical systems (MEMS) research. The use of pulsed laser deposition (PLD) to synthesize PZT offers many advantages over alternative deposition techniques, mainly regarding its ability to...
Recent changes in legislation restricting lead content in waste streams produced during electronics manufacturing have inspired a strong push to develop alternative lead-free materials systems for piezoelectric applications. One lead-free piezoelectric material system, (100-X)Bi₀.₅Na₀.₅TiO₃-XBi₀.₅K₀.₅TiO₃ (BNKT), has shown promising properties in bulk research, however, difficulties have arisen in the development of...