Eelgrass (Zostera marina) provides critical ecosystem functions and services and is a vital biogenic habitat on Washington’s marine aquatic reserves but its placement at the land-sea interface leaves it vulnerable to multiple environmental and anthropogenic stressors. In this study, published scientific literature is examined to identify thresholds of environmental stressors...
As the global demand for seafood increases each year, there is a growing need to expand sustainable aquaculture in the interests of food security and resilience of coastal communities. Pacific oysters, Crassostrea gigas, are grown in West coast estuaries - where cultures often overlap with the federally protected native eelgrass,...
Atomic layer deposition (ALD) is an enabling technique for many new micro- and nanoscale technologies. The self-limiting surface chemical reactions by which ALD fundamentally operates give rise to uniquely high precision (atomic) control over deposited film thickness, uniformity over large areas, and conformality over complex and extreme topographies. One such...
Back end of line (BEOL) metal-insulator-metal capacitors (MIMCAPs) have become a core passive component in modern integrated circuits. International Technology Roadmap for Semiconductors (ITRS) projections for scaling of analog/mixed-signal MIMCAP applications require simultaneously increasing capacitance density while maintaining low leakage current density and low voltage nonlinearity (characterized by the quadratic...
The multifaceted role of the environment in regulating the structure and dynamics of biological communities has long fascinated ecologists and motivated much debate and research. Now, in a time of accelerated global changes due to human impacts, the need to understand how the environment shapes communities has gained new urgency....
The ongoing worldwide loss of biodiversity has been described as a "biodiversity crisis," "the Anthropocene defaunation," and alternatively "an extinction spasm." More recently, many scientists have come to the conclusion that we are witnesses to Earth's sixth major mass extinction event, which has the potential to fundamentally alter basic ecological...
Complex organic transformations, such as the addition of pyrrole to ketene using planar chiral organocatalyst (*PPY), the four-component anhydride- Manniach reactions, and the site-selective desymmetrization of meso-1,2-diol, are remarkable synthetic reactions that provide high yield and high selectivity. However, the exact mechanism and origins of stereocontrol for theses synthetic organic...
Pollution by pesticides is a ubiquitous concern for wildlife. The effects of
pesticides are especially concerning in aquatic environments, which are particularly
vulnerable as they have several exposure routes for the influx of chemicals. These
effects are of particular concern as biodiversity loss reaches unprecedented rates. This
includes recent declines...
A scalable synthesis of the "flat" tridecameric inorganic cluster [Al₁₃(μ₃-OH)₆(μ-OH)₁₈(H₂O)₂₄]¹⁵⁺ has been realized by treating an aqueous aluminum nitrate solution with zinc-metal powder at room temperature. Single crystals and polycrystalline samples are readily obtained in yields exceeding 55% relative to the starting reagent Al(NO₃)₃. Products have been characterized by X-ray...
Many applications in computer graphics and geometry processing rely on the ability to
locally orient 2D and 3D entities on a surface, or inside a volume, such as the sinusoidal
kernels in Gabor noise, the color and geometry textures in pattern synthesis, and the
finite elements in remeshing. In these...