Semi-volatile trace metals like Li, Cu, Mo, Sn, In, and Pb have the potential to track mobility of a volatile phase in volcanic systems. In this dissertation four studies are presented that either directly investigate or are motivated by observations of trace metal behavior in volcanic systems. A common tool...
Oxidized hydrous intermediate composition magmas are responsible for porphyry copper (Cu ±Mo ±Au) deposits and epithermal Au ore deposits formed globally in the shallow crust (Sillitoe, 2010; Seedorff et al., 2005). Recently, zircon geochemistry has been used to characterize both productive and barren intrusions associated with porphyry Cu-Au ore deposits....
Semi-volatile trace metals (e.g., Cd, Sn, Pb, Zn, Cu, Mo) have been analyzed by using laser ablation ICP-MS in a number of silicate glasses (GSE-1G, GSD-1G, NIST 610, NIST 612, BCR-2G, BHVO-2G). Our work investigates and highlights sources of uncertainty in the analysis of semi-volatile metals using LA-ICP-MS. We identify...
The Cretaceous Merín aborted-rift basin of eastern Uruguay is composed of sub-alkaline Paraná-Etendeka province basaltic flows and shallow intrusives (~133 to 131 Ma), rhyolitic ignimbrites (~130 to 128 Ma) and associated mildly alkaline to alkaline intrusions and volcanic rocks (~128 to 127 Ma). Four intrusive complexes from 20 to >30...
Crystal-rich (40-50 vol.%) intermediate lava has been the primary eruptive product of several recent hazardous eruptions: Mt. Pinatubo, Philippines (1991), Soufriere Hills, Montserrat (1995-present), and Unzen, Japan (1990-1995). Despite this association with such devastating eruptions, the formation, timing, and evacuation of such magma is not well understood: do such eruptions...
The Pebble porphyry Cu-Au-Mo deposit in Alaska is one of the world's largest Cu-Au mineral resources. Late Cretaceous magmatic evolution in the Pebble district culminated with the intrusion of the Kaskanak Batholith and associated porphyry copper-gold-molybdenum mineralization. The Kaskanak Batholith is a multiphase granodiorite intrusion with an estimated footprint of...
The subsurface microbial biosphere in the igneous oceanic crust has implications for global geochemical cycling, early life on Earth, and the search for life on Mars. Microscopic evidence of a subsurface microbial ecosystem includes biotic alteration textures associated with basaltic glass. The exact conditions in the basaltic layer that make...
The Hampton Tuff is a 3.9 ± .02 Ma (2σ) ignimbrite sheet from the High Lava Plains of central Oregon. The majority of known outcrops exist to the north, within ~22 mi (~35 km) of the Frederick Butte Volcanic Center, the proposed source of the tuff. Thickness of the tuff...
Constraining the magma evolution and dynamics that lead to the eruption of large volume continental arc systems is fundamental to our understanding of continental crust formation. An investigation into the magmagenesis that results in the formation of the Central Volcanic Zone (CVZ) in the Andes of South America, situated atop...
The volcanic (~45-10 Ma) and plutonic rocks (~37-12 Ma) comprising the Western Cascades extend from northernmost California to southern British Columbia and are ancestral to modern arc magmatism. The ancestral arc hosts a series of small plutons that are locally associated with porphyry (Cu-Mo) and epithermal (Au) ore deposits. Three...