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Creator:: Hurst, James K., Roemeling, Margo D., and Lymar, Sergei V.
Abstract:: One-electron oxidation of the μ-oxo dimer (cis,cis-[Ruᴵᴵᴵ(bpy)₂(OH₂)]₂O⁴⁺, {3,3}) to {3,4} by S₂O₈²⁻ can be described by three concurrent reaction pathways corresponding to the three protic forms of {3,3}. Free energy correlations of the rate constants, transient species dynamics determined by pulse radiolysis, and medium and temperature dependencies of the alkaline...
Resource Type:: Article

Creator:: Hurst, James K., Roemeling, Margo D., and Lymar, Sergei V.
Abstract:: One-electron oxidation of the μ-oxo dimer (cis,cis-[Ruᴵᴵᴵ(bpy)₂(OH₂)]₂O⁴⁺, {3,3}) to {3,4} by S₂O₈²⁻ can be described by three concurrent reaction pathways corresponding to the three protic forms of {3,3}. Free energy correlations of the rate constants, transient species dynamics determined by pulse radiolysis, and medium and temperature dependencies of the alkaline...
Full Text:: SUPPORTING INFORMATION Mechanistic Insight into Peroxydisulfate Reactivity: Oxidation of the cis,cis-[Ru

Creator:: Hurst, James K., Roemeling, Margo D., and Lymar, Sergei V.
Abstract:: One-electron oxidation of the μ-oxo dimer (cis,cis-[Ruᴵᴵᴵ(bpy)₂(OH₂)]₂O⁴⁺, {3,3}) to {3,4} by S₂O₈²⁻ can be described by three concurrent reaction pathways corresponding to the three protic forms of {3,3}. Free energy correlations of the rate constants, transient species dynamics determined by pulse radiolysis, and medium and temperature dependencies of the alkaline...
Full Text:: : Oxidation of the cis,cis-[Ru(bpy)₂(OH₂)]₂O⁴⁺ “Blue Dimer” Mechanistic Insight into Peroxydisulfate

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