This dissertation is separated into two parts according to the two major distinct research projects. In Part I, the full account of synthetic studies toward C10-functionalized lycopodium alkaloids is described. In Part II, the detailed discussion on the exploration of the Pummerer cyclization methodology and its application to the total...
A method was developed to quantify organochlorine pesticides in whale scat. This method would ideally replace analysis of pesticides in blood and tissue samples, which are difficult to acquire. Scat samples were collected from one stranded gray whale and three live whales. The samples were extracted with pressurized liquid extraction,...
Forest soils contain a substantial portion of global terrestrial carbon stores. Forest management can influence the soil carbon pool and how soil organic matter functions. The long-term productivity of forests is an ongoing goal where land managers utilize biomass and timber. A site-specific understanding of intensively managed forests can ensure...
This study investigates the relationship between total and ionic copper in samples taken from the Tualatin River and wastewater treatment facilities (WWTFs) that discharge into the Tualatin River. Copper speciation was analyzed by determining conditional stability constants and densities of copper binding ligands on the dissolved organic matter (DOM) in...
Brown marmorated stink bug (BMSB), (Halyomorpha halys, Hemiptera: Pentatomidae) is an invasive species that damages numerous agricultural crops including grapes. Related damage include lower berry weight with increased exposure and cracked berries as a result of BMSB feeding activity. The insect is currently detected in 43 US states including Oregon,...
Arctic soils are warming, making vast stores of organic carbon available for conversion to CO₂. This could create a positive feedback loop and accelerate global warming, but the processes that convert this carbon into CO₂ are not well understood. We investigated how the combined activities of sunlight and microbes degrade...
Dissolved organic matter (DOM) is a critical component of the carbon cycle linking terrestrial and aquatic ecosystems. Although many factors influence DOM fluxes and quality in rivers, controls on DOM compositions in catchments of the western U.S. are poorly understood. UV and fluorescent spectroscopy is a simpler, faster, and less...
High vegetative growth of Pinot Noir vine is a common problem in most vineyards of Oregon's Willamette Valley, where sunlight exposure and heat accumulation are limited. Consequently, growers in this region commonly use vineyard management strategies to regulate vine vigor and improve grape and wine quality. Wine quality is greatly...
Intimate associations with reactive metal species permanently protect soil organic matter (SOM) from microbial access and oxidation, contributing to the build-up of organic carbon (C) stocks in soils. It is increasingly recognized, however, that such associations can be reversible and that reactive metal species might even facilitate the oxidation of...
This study focuses on one widespread characteristic of poor soil quality: hydrophobic soil. Previous research has produced conclusive evidence to show that soil hydrophobicity is affected by soil organic matter (SOM) and soil water content (WC). Hydrophobicity that responds to changes in WC is a unique form of surface hydrophobicity...