Experiments were designed to answer key questions about diatom-derived organic matter cycling (i.e., production and degradation) in coastal systems. Dissolved organic matter (DOM) production was examined in axenic batch cultures of five diatom species. Dissolved organic carbon (DOC) release rates varied between species, but were significantly higher for all species...
Three approaches toward the core of halichlorine and pinnaic acid are described. The first approach entails a racemic transannular nitrone-olefin [3+2] cycloaddition from nitrone 238. Construction of the nitrone 238 began with aldehyde 241. Another key feature in this route involved a ring-closing metathesis for the formation of a 14-membered...
Hop derived bitter compounds, including alpha-acids, reduced and non-reduced iso-alpha-acids, were evaluated for their contribution to peak bitter intensity in lager beer. Alpha-acids are the precursors to the major bittering components in beer (iso-alpha-acids). Typically, alpha-acids do not survive the brewing process, but if a product is dry-hopped, they may...
SOCs volatility and persistence properties cause many SOCs to become ubiquitous in the environment as well as accumulate in areas with lower temperatures such as polar or orographic regions. Many anthropogenic SOCs pose a serious risk to human and ecosystem health because of their persistent, bioaccumulative, and toxic properties in...
This report presents results of an investigation of water and streambed-sediment quality in selected tributaries of the South Umpqua River. Concentrations of inorganic constituents in water (major and minor ions, nutrients, and trace elements) and streambed sediment (primarily trace elements), along with standard field parameters, are tabulated for samples collected...
The specific objectives of this dissertation are to determine subsurface flow
behaviors across different antecedent wetness conditions from a top-down perspective
and to mechanistically assess the hydrological controls on DOC and N transport at the
hillslope and catchment scale. The study area is a small catchment where hillslopes
issue directly...
The atmospheric transport of anthropogenic semivolatile organic compounds (SOCs) from Asian sources to the Western U.S. was investigated. In addition, the SOC extraction method was optimized. Hansen solubility parameter plots were used to aid in the pressurized liquid extraction (PLE) solvent selection of air sampling media in order to minimize...
More than 65,000 organic chemicals are currently in commercial production with
approximately 1000 added each year. Many chemicals are released into the environment as organic mixtures derived from complex hazardous or solid wastes. Of these, more than 1000 chemicals are of environmental concern because of their production quantities, toxicity, persistence,...