An increase in anthropogenic activities since the industrial revolution, primarily due to burning of fossil fuels and changes in land cover, has resulted in a steady increase in the global mean atmospheric CO2 concentrations. While there is unequivocal scientific evidence on global warming and its multidimensional impacts on natural and...
Understanding the processes that control the terrestrial exchange of carbon is critical for
assessing atmospheric CO₂ budgets. Carbonyl sulfide (COS) is taken up by vegetation during
photosynthesis following a pathway that mirrors CO₂ but has a small or nonexistent emission component,
providing a possible tracer for gross primary production. Field...
This article examines the influence of Emmanuel Levinas’s philosophy on the ethical aspects of the life and work of André Schwarz-Bart. The essay is framed through recent re-interest in Schwarz-Bart’s collaborative works with his wife, Simone, as a bridge between Holocaust and postcolonial studies. The publications, arguments, and key points...
The vast marine deep biosphere consists of microbial habitats within sediment, pore waters, upper basaltic crust and the fluids that circulate throughout it. A wide range of temperature, pressure, pH, and electron donor and acceptor conditions exists—all of which can combine to affect carbon and nutrient cycling and result in...
More than 30 members of the diverse amphidinolide family of biologically active macrolides have been isolated over last three decades. From this family, amphidinolides C and F stand among the most complex and densely functionalized affiliates. Recently, we have accomplished the first total synthesis of amphidinolide F. The all-carbon framework...
The diurnal fluctuations in solar irradiance impose a fundamental frequency on ocean biogeochemistry. Observations of the ocean carbon cycle at these frequencies are rare, but could be considerably expanded by measuring and interpreting the inherent optical properties. A method is presented to analyze diel cycles in particulate beam-attenuation coefficient (c[subscript...
Outcrops of old strata at the shelf edge resulting from erosive gravity‐driven flows
have been globally described on continental margins. The reexposure of old strata allows
for the reintroduction of aged organic carbon (OC), sequestered in marine sediments for
thousands of years, into the modern carbon cycle. This pool of...
The structural architecture present in marine toxin azaspiracid - 20 stereocenters, 9 rings, 3 separated spirocenters - has attracted considerable synthetic attention. Our efforts toward the synthesis of azaspiracid have led to the completion of both C₁-C₂₆ northern and C₂₇-C₄₀ southern halves. Herein, the
synthesis of southern FGHI ring system...
Thomas Stearns Eliot’s 1922 modernist poem The Waste Land presents itself as an alternative to the decaying society Eliot found himself inhabiting. It begins as a personal means of pulling together one’s fragmented consciousness, but in doing so Eliot manages to present a solution to a world of selfishness—looking beyond...
The central purpose of this dissertation was to explore and expand the use of
an uniform electric field for orientation and for subsequent spectroscopic investigation of asymmetric polar molecules in the gas phase. The systems of study were nitrobenzene (NB) and the nitrotoluene (NT) isomers. We were able to quantitatively...