Infiltration of highly concentrated solutions into unsaturated sand is suspected to be affected by the liquid-gas interfacial tension between the resident water and that of the infiltrating solution. The wetting of non-porous solid surfaces by liquids is commonly quantified by contact angle measurements. However, it is well known that wettability...
Liquid saturation and gas-liquid interfacial area are important parameters for evaluating the transport and fate of contaminants in unsaturated subsurface environments. Recent findings indicate that interfacial surface area controls the relative degree of transmitted light in laboratory systems containing translucent porous media. Equations are derived to estimate the specific gas-liquid...
Water vapor transport in the vicinity of imbibing saline solutions was investigated in two-dimensional (2-D) chambers using a light transmission technique. Concentrated NaNO3 solutions (brines) were applied as point sources to the surface of homogenous packs of prewetted silica sand for four different sand grades. The same solutions were applied...
Using thermodynamic principles, the general relationship describing the equilibrium vapor content in the gas phase above a saline liquid and across a curved liquid-gas interface is developed. Since high salt concentration also affects the intensive and extensive liquid properties, it is also necessary to account for these effects in liquid...
Evaporation from bare soil was investigated using a numeric model In one set of simulations, texture and evaporative demand were analyzed as they impacted short and long term evaporation. The effect of these factors on water redistribution was also analyzed. A second set of simulations was run to determine the...
Non-dilute salt strength solutions occur in many near surface geologic environments. In order to better understand the occurrence and movement of the water and salt, mathematical models for this non-ideal fluid need to be developed. Initial boundary value problems may then be solved to predict behavior for comparison with observations....
Though many arid and contaminated sites have high salinity, prediction of effects of salinity on water movement in soils has been based on dilute solution approximations. Here a sensitivity analysis compares predicted liquid and vapor pressure in variably saturated porous media found using both the dilute approximations and a more...
Surface tensions of high-salinity solutions are significantly different from those of pure water. Our objective was to develop and test a methodology to determine whether these surface tension effects predictably alter imbibition into dry and moist porous media. Static and dynamic experiments were performed using four grades of quartz sand...
Colloids, particles smaller than ten microns in diameter, are ubiquitous in the subsurface. Colloids have an effect on the transport of contaminants that bind to their surfaces, and can reduce the permeability of aquifer materials through deposition. Some microorganisms, including pathogens, are also transported in the subsurface as colloids. The...
Evaporation of saline solutions from porous media, common in arid areas, involves complex interactions between mass transport, energy exchange and phase transitions. We quantified evaporation of saline solutions from heterogeneous sand columns under constant hydraulic boundary conditions to focus on effects of salt precipitation on evaporation dynamics. Mass loss measurements...