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Radical and related reactions of aromatic species

Creator:: Truska, Scott
Abstract:: A three part study involving aspects of radical properties of various aromatic species was accomplished. Experiments to ascertain the importance of geometric and electronic effects on the intramolecular transfer of a pi-complexed radical to a terminal double bond was performed. Several 4-aryl-1-butenes were reacted in competition with 1-undecene with a...
Resource Type:: Dissertation
Full Text:: Reactions of Aromatic Species. Abstract approved: Gerald Jay Gleicher A three part study involving

P-xylene as a starting material in the preparation of P-toluic acid, terephthalic acid and their derivatives

Creator:: Yen, Shou-hsuan
Resource Type:: Masters Thesis

Homolytic aromatic substitution : substituent effects in the radical trichloromethylation of 9-X-anthracenes

Creator:: Arnold, James Charles
Resource Type:: Masters Thesis
Full Text:: compound exhib- its the highest reactivity of all the compounds in the series. This is interpreted as due

The aromatic Cope rearrangement : energetics and reality

Creator:: Almond, Stephen W.
Resource Type:: Dissertation
Full Text:: Approximate Resonance Energies) from Heats of Combustion of Some Aromatic C(.mpounds (Ref. 26). Compound

Kinetic study of Si(NH) synthesis via low temperature vapor phase reaction of SiCl and NH in a fluidized bed reactor

Creator:: Hsu, Chia-Chang, 1967-
Resource Type:: Masters Thesis
Full Text:: , roentgen- amorphous white powder which was the most typical compound of Si(NH)2. The reaction was

An analytical and sensory evaluation of the aroma volatiles of Tuber gibbosum

Creator:: Marin, Anna B.
Abstract:: The aroma of Tuber gibbosum, a native Oregon truffle, was characterized using two distinct techniques. Volatile aroma constituents were identified by chemical analysis, and sensory characteristics were determined by examining response of the general populace to the truffle aroma. Truffle samples from four maturity ranges, as determined by microscopic examination...
Resource Type:: Masters Thesis
Full Text:: Italian white truffle. Tuber magnatum and found to be the character-impact compound for that truffle

Dechlorination of p-chlorophenol on bimetallic Pd/Fe catalyst in a magnetically stabilized fluidized bed : experiment and theory

Creator:: Graham, Lisa Jean
Resource Type:: Dissertation

Photochemistry of some bromoarenes

Creator:: Jang, Jung-suk
Abstract:: The photodebromination of selected bromoarenes has been studied at 300 nm to determine the the possible mechanistic pathways leading to product. Irradiation of 4-bromobiphenyl (BpBr) at this wavelength leads to the product biphenyl. The quantum yield of intersystem crossing (0.98) and quenching studies with cis-1 ,3-pentadiene suggest that the reaction...
Resource Type:: Dissertation
Full Text:: Bromoarenes Chapter I. Introduction Aromatic halides find important and diverse applications in such areas

A Diels-Alder approach to biaryl synthesis

Creator:: Ashburn, Bradley O.
Abstract:: An expedient approach to the synthesis of a wide range of highly programmable biaryl templates has been accomplished. Utilizing the Diels-Alder [4+2] cycloaddition, a wide range of tri- and tetra-ortho-substituted biaryls have been synthesized in only three to four steps from commercially available materials. We have successfully synthesized entire classes...
Resource Type:: Dissertation
Full Text:: biaryl portion of the anti-cancer compound TMC- 95 provided the groundwork for our current methodology

Synthesis, characterization, and analysis of nitroaromatic compounds

Creator:: McIntosh, Melissa Luana
Abstract:: Nitroaromatic compounds have important chemical applications and can be found in nature as pollution sources. Synthetic nitroaromatic compounds have been used in a variety of materials including explosives, pharmaceuticals, dyes, plastics, and pesticides. These compounds can find their way into the environment through normal or improper disposal methods. Poly-aromatic compounds...
Resource Type:: Masters Thesis
Full Text:: . Poly-aromatic compounds are important structural motifs due to their presence in complex natural

ScholarsArchive@OSU

Radical and related reactions of aromatic species

P-xylene as a starting material in the preparation of P-toluic acid, terephthalic acid and their derivatives

Homolytic aromatic substitution : substituent effects in the radical trichloromethylation of 9-X-anthracenes

The aromatic Cope rearrangement : energetics and reality

Kinetic study of Si(NH) synthesis via low temperature vapor phase reaction of SiCl and NH in a fluidized bed reactor

An analytical and sensory evaluation of the aroma volatiles of Tuber gibbosum

Dechlorination of p-chlorophenol on bimetallic Pd/Fe catalyst in a magnetically stabilized fluidized bed : experiment and theory

Photochemistry of some bromoarenes

A Diels-Alder approach to biaryl synthesis

Synthesis, characterization, and analysis of nitroaromatic compounds

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