We report an experimental and theoretical study of single-molecule inner-shell photoemission measured over an extended range of photon energies. The vibrational intensity ratios I (nu = 1)/I (nu = 0) from the C 1s photoelectron spectra of carbon monoxide, although mostly determined by the bond length change upon ionization, are...
Magmatic-hydrothermal ore deposits are giant geochemical anomalies in the earth’s crust most often generated by normal magmatic terrestrial processes. They are often associated with oxidized and hydrous intermediate to highly evolved magmas that have concentrated metals and have the necessary components to efficiently extract and transport them as ascending magmatic-hydrothermal...
Air pollution and pollution patterns have become a hot topic over the last several years. Many studies have been launched due to the increasing concern with air quality. As urban areas grow, atmospheric heavy metal pollution grows proportionally. Reducing atmospheric heavy metal pollution, and consequent health issues, requires monitoring and...
Metagenomics has revealed that the marine microbial biosphere is immensely more diverse than originally considered, and is an almost untapped reservoir for the potential discovery of microbial natural products. Despite numerous advances in culturing, biosynthetic engineering and genomic-based screening efforts to uncover much of this diversity in relatively accessible environments,...
Analytical chemistry is an essential qualitative and quantitative tool to describe foods and biomaterials and their changes during production, processing and distribution. In this work, rapid analytical procedures for the extraction and quantification of components in fluid milk and diatom fermentation broth were developed. Analytical methods to measure the concentration...
Increasingly popular methods for managing impacts of tourism in nature-based settings include collaborative and voluntary codes of conduct. In southeast Alaska, for example, the Tourism Best Management Practices (TBMP) in Juneau and Wilderness Best Management Practices (WBMP) in Tracy Arm-Fords Terror Wilderness have been created to address shore and marine...
The effect of the Coriolis interaction upon the sharing of energy between rotational and vibrational excitation
during an electronic transition is considered with particular emphasis on recoil-induced excitation during
photoionization. If there is a large change in equilibrium bond length upon ionization, then Coriolis coupling
leads to a significant transfer...
The interface between a biofilm and the underlying substrate to which it is attached is challenging to study. Currently, available methods of studying this microenvironment have not been able to record data in real-time over a time period in the range of days. To address this challenge, we report the...
The hygiene hypothesis offers an explanation for the correlation, well-established in the industrialized
nations of North and West, between increased hygiene and sanitation, and increased rates of asthma and
allergies. Recent studies have added to the scope of the hypothesis, showing a link between decreased
exposure to certain bacteria and...
An understanding of creativity’s emergence is critical as our society faces new challenges. Despite a growing body of research emphasizing nature’s influence on the creative process, we now spend record amounts of time indoors, disconnected from nature. Biophilic design has been afforded as a panacea, with research supporting the incorporation...