New transparent p- and n-type semiconductors and luminescent materials have been prepared and characterized. Synthesis, structures, optical and electrical properties of new chalcogenide fluoride p-type transparent semiconductors MCuQF (M=Ba, Sr; Q=S, Se, Te) are described. Band-gap tuning and improvement in conductivity through p-type doping are demonstrated in the family. The...
Bulk properties of CuSc₁₋ₓMgₓO₂, CuSc₁₋ₓMgₓO₂₊y, BaCu₂S₂, Bai₁₋ₓKCu₂S₂, BaCu₂Se₂
and Bai₁₋ₓKₓCu₂Se₂ are investigated supporting the search for highly conductive p-type
thin films. Mg is an efficient dopant in CuScO₂ with conductivity up to l.5.10⁻² S/cm.
Oxidation of CuScO₂:Mg leads to further increase in conductivity up to 0.5 S/cm. The
amount of...
Crystals of CdF₂:In and CdF₂:Ga reduced in a cadmium vapor exhibit unusual
metastable properties that can be explained by a "negative U" model. This work
uses NMR to investigate this model for CdF₂:Ga and CdF₂:Ga,Y and compare the
results to optical measurements. Temperature dependent relaxation measurements
were done on ¹¹³Cd...
The electrical and optical properties of semi-insulating, epitaxial and ion-implanted GaAs and InP have been characterized and analyzed. Electron and hole traps in semi-insulating GaAs and InP, with activation energies ΔE[subscript T] ranging from 0.16 ± 0.01 to 0.98 ± 0.01 eV, have been detected and characterized by Photo-Induced Current...
The results of an investigation into carrier dynamics in several novel functionalized and solution-processable pentacene and anthradithiophene derivatives are reported. Measurements were made of real-time photoresponse of polycrystalline thin films of these materials to ultrafast laser pulses, on picosecond to microsecond time-scales, as well as measurements of dark current and...
The behavior and application of organic semiconductor materials depend strongly on their molecular structure, and molecular interactions. Several studies of intermolecular interactions in functionalized polyacene materials are presented. The degree and onset of aggregation of a functionalized anthradithiophene derivative was studied as a function of concentration in two different host...
The continued development of organic semiconductor materials relies on an understanding of the relationship between optoelectronic properties, molecular structure, and molecular interaction. Several detailed studies of electronic properties in functionalized polyacene materials are presented. A computational model which allows the extraction of charge generation and transport properties from experimental data...
This thesis will cover my work relating to the developing field of terahertz (THz) science and technology. It will present experimental and theoretical studies investigating the optical and electrical properties of various material systems using novel THz imaging and spectroscopy techniques. Due to its low photon energy, THz imaging and...
Mercury cadmium telluride is important in the detection
of electromagnetic radiation in the eight to twelve micron
atmospheric window for infrared imaging systems. High
resolution infrared imaging systems use either large (256x256
element to 1024x1024 element) staring arrays or much smaller
(1-6 element) scanned arrays in which the image is...