Diclofop (2- [4 -(2, 4-dichlorophenoxy)phenoxy] propanoic
acid), formulated as the methyl ester, selectively kills
barnyardgrass [Echinochloa crus -galli (L.) Beauv.] in several
crops when applied postemergence. Studies were conducted
to determine the effect of soil moisture, barnyardgrass age, and site of exposure on control of barnyardgrass with diclofop. Soil moisture...
The photochemistry of some analogs of insect growth regulators
(IGR's) was studied. Methyl geranate, TY, was synthesized and the
mechanisms of its photochemical reaction pathways were studied by a
variety of techniques. Direct irradiation of 71 in ether leads to the
formation of five new products: 98, the product of...
The stereospecific reagent-controlled homologation (StReCH) of boronic esters with putative lithiooxiranes generated in situ from appropriate precursors via sulfoxide-lithium exchange, tin-lithium exchange, and direct lithiation is described with an emphasis on the first lithiation technique which allows for the regio- and stereo-specific generation of all types of lithiooxirane isomer. Transient...
The creation of new semi-interpenetrating polymer networks (semi-IPNs) was attempted using miscible blends of high molecular weight cellulose esters (CE) and low molecular weight polyvinylphenol (PVP) with various initiators for the crosslinking reaction. Blends of cellulose acetate (CA) or cellulose acetate butyrate (CAB), at 50/50, 70/30, and 90/10 wt%CE/wt% PVP...