The synthesis of isoindazoles bearing α-ketoester and α-hydroxyester groups via the coarctate cyclization of ester terminated azo-ene-yne precursors is described. Whereas previous studies on isoindazole formation have shown the reaction to proceed through a kinetic coarctate pathway, functionalization of the terminal acetylene with a methyl ester sufficiently stabilizes the carbene...
We examined sub-nanosecond time-scale charge carrier dynamics in crystalline films of a functionalized anthradithiophene (ADT) donor (D) with three different acceptor (A) molecules. A four-fold enhancement in ultrafast charge carrier separation efficiency was observed in D/A blends with a fullerene acceptor added at 7–10 wt. % concentrations, whereas a gradual...
Growing concerns over the rise of anthelmintic resistant populations of gastrointestinal nematodes (GINs) have led producers to look for alternative means of treatment. These sentiments have been echoed by organic producers, who are restricted from the use of synthetically derived anthelmintics in the US. Chicory has emerged as a potential...
Hostile sexism (HS) is an antagonistic attitude towards women; benevolent sexism (BS) is a positive attitude towards women that is sexist in terms of viewing women in restricted roles. HS and BS held simultaneously is defined as ambivalent sexism (AS). Despite negative outcomes associated with AS, BS, and HS, women...
This thesis is the combination of two research publications working toward a unified strategy in which to represent complex engineered systems as complex networks. Current engineered system modeling techniques segment large complex models into multiple groups to be simulated independently. These methods restrict the evaluations of such complex systems as...
The primary Mg/Ca ratio of foraminiferal shells is a potentially valuable paleoproxy for sea surface
temperature (SST) reconstructions. However, the reliable extraction of this ratio from sedimentary calcite
assumes that we can overcome artifacts related to foraminiferal ecology and partial dissolution, as well as
contamination by secondary calcite and clay....
Methane fluxes into the oceans are largely dependent on the methane phase as it migrates upward through the sediments. Here we document decoupled methane transport by gaseous and aqueous phases in Storfjordrenna (offshore Svalbard) and propose a three-stage evolution model for active seepage in the region where gas hydrates are...
Mg/Ca ratios in planktonic foraminifera reflect calcification temperatures and are thus useful for sea
surface temperature (SST) reconstructions. Despite the obvious utility of this paleoceanographic tracer,
problems of dissolution, gametogenic calcification, and contaminant phases have thus far limited
confidence in Mg/Ca-based reconstructions. Here we show strong evidence of Mg heterogeneity...
Multiproxy geologic records of δ18O and Mg/Ca in fossil foraminifera from sediments under the Eastern Pacific Warm Pool (EPWP) region west of Central America document variations in upper ocean temperature, pycnocline strength, and salinity (i.e., net precipitation) over the past 30 kyr. Although evident in the paleotemperature record, there is...
Analytical challenges in obtaining high quality measurements of rare earth elements (REEs) from small pore fluid volumes have limited the application of REEs as deep fluid geochemical tracers. Using a recently developed analytical technique, we analyzed REEs from pore fluids collected from Sites U1325 and U1329, drilled on the northern...