Porous silicon oxycarbide (SiOC) beads were prepared by freeze-drying of water-in-oil (w/o) emulsion, containing water and polycarbosilane (PCS) dissolved p-xylene in the presence of sodium xylenesulfonate (SXS) as an emulsifier. The emulsion was frozen by being dropped onto a liquid N₂ bath, which resulted in 1~2 mm sized beads. After...