This study investigated the use of radon-222 as an in situ partitioning tracer for quantifying nonaqueous phase liquid (NAPL) saturations in the subsurface. Laboratory physical aquifer models (PAMs), field experiments, and numerical simulations were used to investigate radon partitioning in static (no-flow) experiments and in single-well, 'push-pull' tests conducted in...
Two separate research projects are described here. One involves
development of a new analytical method for determination of Ba in seawater and
other natural waters. The other is a collaborative field study of the chemistry of
Lake Issyk-Kul, Kyrgyzstan.
The method project explored an ion chromatography-fluorescence detection
bench-top approach for...
The spatial organization of farm units in Polk and Linn counties
in the mid-Willamette Valley has undergone significant change over
the past 30 years. Whereas most study areas operations in the
1930's and 1940's consisted of small family owned farms with contiguous
land bases, present mid-Willamette Valley units vary considerably...
Neptunium, with its rich redox chemistry, has a special position in the chemistry of actinides. With a decades-long history of development of aqueous separation methods for used nuclear fuel (UNF), management of neptunium remains an unresolved issue because of its not clearly defined redox speciation. Neptunium is present in two,...
The DNA-binding domains of E. coli uracil-DNA glycosylase (Ung) and human replication protein A (hRPA) were studied using a general protocol developed in our laboratory for probing protein-DNA interactions. The procedure involves purification and mass spectrometric analysis of the nucleopeptide-products of a tryptically digested UV-crosslinked protein-nucleic acid complex. In the...
In proteomic studies, separate experimental protocols have been necessary to identify proteins, determine their function, and predict their three-dimensional structure. In this study, a function-based separation of proteins was conceived to fractionate proteins prior to enzymatic digestion. In the initial demonstration of this technique, a DNA substrate was used to...
Over the last decade, the miniaturization of analytical systems has become an increasingly important and interesting research area. Miniaturized systems offer many advantages, including reduced reagent and sample consumption, shorter analysis times, portability and disposability. This dissertation describes novel approaches in this direction, focusing on two areas: the miniaturization of...
This study dealt with research problems at the landscape level. The objectives of this thesis were to develop tools to study and characterize landscapes and to interface with a geographic information system (GIS), to evaluate landscape indices, and to examine development of forest cutting patterns under different cutting methods and...