The potassium salts of certain 1-vinylcycloalk-3-en-l-ols have
been found to undergo sigmatropic ring expansion rearrangements in
HMPA. Preliminary investigations of several benzo-substituted medium
ring systems were undertaken in order to determine which of these
was best suited for further study. A synthetic sequence leading to
the formation of 5-methy1-6-viny1-7,8,9,10-tetrahydro-6-benzocyclo-octenol,
which...
Three areas of liquid state theory are considered.
First, Monte Carlo computer simulation of a two-dimensional hard
disk fluid with an imbedded ellipse was undertaken to determine how a
non-spherical molecule affects intermolecular ordering. The
elliptical molecule (with axial ratios of 2, 5 and 10) altered the
isotropic distribution of...
Satellite data from the Geosat altimeter and the Advanced Very High Resolution Radiometer (AVHRR) are used to show the large-scale structure of the surface circulation of the California Current System in summer. These data show the connection between an equatorward jet and temperature front off Oregon that lies within 100...
We examine large-scale atmospheric behavior around the time of the spring and fall transitions in the coastal ocean off the west coast of North America. Records of adjusted sea level (ASL), coastal wind stress, sea level atmospheric pressure (SLP), and 500-mbar heights for the years 1971-1975 and 1980-1983 are analyzed....
Surface transports into the California Current are calculated from TOPEX/POSEIDON altimeter surface height slopes during the 9.5 year period from October 1992–May 2002. These quantify the anomalous onshore and southward displacements of the water column during the 2000–2002 period, which had been hypothesized by others based on anomalous water properties...
Data from Geosat and TOPEX altimeters are used to infer the structure of the Peru-Chile Countercurrent, a jet that flows from at least as far north as 10ºS (historical data suggests 7ºS) to 35º–40ºS, maintaining its position between approximately 100–300 km offshore. Although the annual mean current cannot be determined...
Satellite-derived pigment concentrations from the west coast time series (WCTS) are averaged into monthly mean fields over the California Current system (CCS) for the period July 1979 to June 1986. Errors caused by the scattering algorithm used in the WCTS are reduced by an empirical correction function, although winter values...
Concurrent satellite-measured chlorophyll (CHL), sea surface temperature (SST), sea level anomaly (SLA) and model-derived wind vectors from the 13+ year SeaWiFS period September 1997 – December 2010 quantify time and space patterns of phytoplankton variability and its links to physical forcing in the Pacific Ocean. The CHL fields are a...
Altimeter sea surface height (SSH) fields are analyzed to define and discuss the seasonal circulation
over the wide continental shelf in the SW Atlantic Ocean (27°–43°S) during 2001–2012. Seasonal variability
is low south of the Rio de la Plata (RdlP), where winds and currents remain equatorward for most of
the...
Full Text:
Altimeter-Derived Seasonal Circulation on the Southwest Atlantic Shelf: 27° – 43°S
P. Ted Strub1, Corinne
Altimeter sea surface height (SSH) fields are analyzed to define and discuss the seasonal circulation
over the wide continental shelf in the SW Atlantic Ocean (27°–43°S) during 2001–2012. Seasonal variability
is low south of the Rio de la Plata (RdlP), where winds and currents remain equatorward for most of
the...
Full Text:
shelf: 278–438S
P. Ted Strub1, Corinne James1, Vincent Combes1, Ricardo P. Matano1, Alberto R. Piola2