Transition metal oxides exhibit potential in various application fields due to the special d-electrons. Solid state chemistry focuses on discovering the structure-property relationships. The work in this thesis mainly discusses compounds with hexagonal or brownmillerite-type structure and their practical properties.
Hexagonal YIn[subscript 1-x]Fe[subscript x]O₃ (x = 0-0.3, 0.7-1.0) phases have...
This study investigates methods of multivariate regression analysis and their applications to biological data. It provides an overview of methods of reduced rank regression and sparse multivariate regression, including their motivations, methods, and applications. It also implements a form of sparse regression known as Regularized Multivariate Regression for Identifying Master...
The OSU global coupled atmosphere/ocean general circulation
model (A/O GCM) has been used to simulate the present (lxCO₂)
climate and to investigate a CO₂-induced (2xCO₂) climate change.
Previous analysis of the lxCO₂ simulation showed distinct errors in
the simulated sea surface temperature (SST) and sea ice which were
attributed primarily...
In the 21st century, environmental deterioration is now an indisputable fact. Reliable and economically viable electricity systems based on renewable sources are urgently needed to replace the environmentally detrimental fossil fuels. The feasibility of incorporating renewable-but-intermittent solar and wind energy heavily depends on the development of cost-effective and safe technologies,...
We consider two semiparametric regression models for data analysis, the stochastic additive model (SAM) for nonlinear time series data and the additive coefficient model (ACM) for randomly sampled data with nonparametric structure. We employ the SCAD-penalized polynomial spline estimation method for estimation and simultaneous variable selection in both models. It...
Crystals of an incongruent-melting compound, Ba₃MgSi₂O₈, were grown by the flux method and its structure was determined by single crystal X-ray diffraction methods. Ba₃MgSi₂O₈ crystallizes in trigonal space group P-3[bar]m1 with a = 5.6123(3) Å, c = 7.2667(9) Å and Z = 1. Eu²⁺ ions prefer one crystallographic Ba site...
Hexagonal AMO₂ and AMO₃ phases have the same basic structure, and intermediate compositions for this structure have been prepared by topotactic oxidation of AMO₂ phases such as RCuO₂, where R is a trivalent rare earth cation. We now find that such intermediate phases can also be prepared by topotactic reduction...
The discovery of a brilliant-blue color upon the introduction of Mn³⁺
to the trigonal-bipyramidal (TBP) sites in YInO₃ has led to a search for other hosts
for Mn³⁺ in TBP coordination. An obvious choice would be YAlO₃. This compound,
which has only been prepared through a citrate precursor route, has...
Full Text:
,† Andrew E. Smith,† PengJiang,† Judith K. Stalick,‡ Arthur W. Sleight,† and M. A. Subramanian
The discovery of a brilliant-blue color upon the introduction of Mn³⁺
to the trigonal-bipyramidal (TBP) sites in YInO₃ has led to a search for other hosts
for Mn³⁺ in TBP coordination. An obvious choice would be YAlO₃. This compound,
which has only been prepared through a citrate precursor route, has...
The discovery of a brilliant-blue color upon the introduction of Mn³⁺
to the trigonal-bipyramidal (TBP) sites in YInO₃ has led to a search for other hosts
for Mn³⁺ in TBP coordination. An obvious choice would be YAlO₃. This compound,
which has only been prepared through a citrate precursor route, has...
