Sediments from five Leg 167 drill sites and three piston cores were analyzed for C[subscript ORG] and CaCO₃. Oxygen isotope stratigraphy on benthic foraminifers was used to assign age models to these sedimentary records. We find that the northern and central California margin is characterized by k.y.-scale events that can...
A stable-isotope stratigraphy at Site 846 (tropical Pacific, 3°06'S, 90°49'W, 3307 m water depth), based on the benthic
foraminifers Cibicides wuellerstorfi and Uvigerina peregrina, yields a high-resolution record of deep-sea δ¹⁸O and δ¹³C over the
past 1.8 Ma, with an average sampling interval of 3 k.y. Variance in the δ¹⁸O...
Phospholipase C-β (PLC-β) isozymes are key effectors in G protein-coupled
signaling pathways. Prior research suggested that some isoforms of PLC-β may exist
and function as dimers, but little is known about dimerization of PLC-β. Data from coimmunoprecipitation
assays of differentially-tagged PLC-β constructs and sizeexclusion
chromatography of native PLC-β support homodimerization...
1. The recommended allowance of the National Reasearch
Council, 100 mg ascorbic acid for the 18-year-old boys and 80 mg
for the 16 to 19-year-old girls, did not maintain mean plasma ascorbic
acid values at levels as high as the respective saturation means. For
the girls all the mean values...
A rheostat is an adjustable resistor so constructed that its resistance may be changed without opening the circuit in which it may be connected. Conventional rheostats are adjusted mechanically. This thesis presents a method of adjusting resistance electrically by varying the light intensity incident on the surface of a photoconductive...
The sorbed gases at all four Ocean Drilling Program Leg 139 sites (855, 856, 857, and 858) showed the unmistakable presence of thermogenic hydrocarbons. No indication of abiogenic gas was found. The evidence for the thermogenic hydrocarbons includes elevated contents of higher hydrocarbons (i.e., C₁/[C₂ + C₃] ca. 2-20), δ¹³CCH₄...
High-temperature combustion oxidation measurements of nonvolatile dissolved organic carbon (DOC) have been determined for pore waters from sediments of Middle Valley, Ocean Drilling Program Leg 139, as well as for overlying and near-bottom seawater. The DOC values in the interstitial waters are generally greater than those in the overlying water...
The accelerated diagenesis, maturation, and catagenesis of organic matter to hydrothermal petroleum was studied in sediments from Ocean Drilling Program Leg 139 in Middle Valley, northern Juan de Fuca Ridge. Sediments at Sites 855 and 856 have experienced high heat flow resulting in accelerated diagenesis of the immature organic matter...
This dissertation is separated into two parts according to the two major distinct research projects. In Part I, the full account of synthetic studies toward C10-functionalized lycopodium alkaloids is described. In Part II, the detailed discussion on the exploration of the Pummerer cyclization methodology and its application to the total...