Organic semiconducting materials have emerged in the last few decades as viable alternatives to inorganics in broad applications from field effect transistors to LEDs to solar cells. Organics provide many benefits over inorganics such as flexibility, sustainability, and reduced cost. However, these materials are more susceptible to degradation in the...
Exciton polaritons are quasiparticles composed of a quantum superposition of matter and light states that arises from the coupling of a standing wave photon and an exciton. This research has two primary objectives: to design and fabricate a Fabry-Perot microcavity system in which to produce exciton polaritons; and to show...
This project investigated transient photoconductivity in organic donor-acceptor (D-A) systems, where a flourinated anthradithiophene, ADT-TES-F, acts as the donor. Various acceptor molecules were used, with different sidegroups, and different HOMO (highest occupied molecular orbital) and LUMO (lowest unoccupied molecular orbital) energy level offsets relative to the acceptor. Thin film composites...
Understanding charge transfer in organic semiconductors is important for developing devices like organic light emitting diodes and flexible electronics. Optical tweezers have been used in many disciplines for trapping, manipulating, and analyzing microscopic objects such as microspheres, micro-organisms, and other colloidal particles. Using optical tweezers, studies have measured the average...
We present a report on a new capability for low temperature microscopy of organic
optoelectronic semiconductor materials. We may now perform photoluminescence (PL) and
conductivity measurements as a function of temperature on a microscopic level.
Testing confirmed the setup's ability to support microscopic measurements at pressures
of 10^-6 Torr and...
Optical trapping is a tool used throughout a wide variety of disciplines rang- ing from precisely probing and manipulating sub-micron organisms in biol- ogy to analyzing fundamental charge transfer in colloidal physics. This thesis presents research involving optical tweezer force measurements of polystyrene and silica microspheres. In addition, preliminary work...
Improvements on the charge control measurements of the torsion pendulum, electron gun, and autocollimator system were conducted at the University of Washington in preparation for the fabrication of the final prototype of the Laser Interferometer Space Antenna (LISA) gravitational wave detector for NASA. One main cause of transient forces on...
We explore the interactions between charge transfer exciton states (CTEs) and an optical microcavity by testing the effects that cavity resonance has on the CTEs and if CTEs can be coupled with a photon to create quasiparticles known as polaritons. Exciton polaritonics is becoming a booming area of research mainly...
Studies of light-matter interactions in organic semiconductors and in optical tweezer trapping of nanoparticles are presented. In the research related to organic semiconductor materials, a variety of novel materials and their composites have been characterized, and physical mechanisms behind their optoelectronic properties have been established. Three novel functionalized hexacene derivatives...
The behavior and application of organic semiconductor materials depend strongly on their molecular structure, and molecular interactions. Several studies of intermolecular interactions in functionalized polyacene materials are presented. The degree and onset of aggregation of a functionalized anthradithiophene derivative was studied as a function of concentration in two different host...