More than 65,000 organic chemicals are currently in commercial production with
approximately 1000 added each year. Many chemicals are released into the environment as organic mixtures derived from complex hazardous or solid wastes. Of these, more than 1000 chemicals are of environmental concern because of their production quantities, toxicity, persistence,...
Sources of polar/water-soluble organic compounds conjunctly with apolar biomarkers were characterized in natural organic matter. This multi-biomarker approach was accomplished by a simple analytical method consisting of extraction with dichloromethane:methanol (2:1, v/v), silylation and analysis by gaschromatography- mass spectrometry (GC-MS). Polar and apolar biomarkers, derived mainly from higher plants and...
The atmospheric transport of anthropogenic semivolatile organic compounds (SOCs) from Asian sources to the Western U.S. was investigated. In addition, the SOC extraction method was optimized. Hansen solubility parameter plots were used to aid in the pressurized liquid extraction (PLE) solvent selection of air sampling media in order to minimize...
Volatile hydrophobic compounds (HOCs) brought into soil and sediment
systems represent a serious threat to the environment. Dissolved
organic carbon (DOC) may exert an important influence over the total
aqueous solubility and mobility of organic pollutants through their
incorporation into micelles or the formation of soluble complexes.
To date, however,...
Experiments were designed to answer key questions about diatom-derived organic matter cycling (i.e., production and degradation) in coastal systems. Dissolved organic matter (DOM) production was examined in axenic batch cultures of five diatom species. Dissolved organic carbon (DOC) release rates varied between species, but were significantly higher for all species...
Ambient high-volume (hi-vol) air samples were collected between March 15th and May 30th 2002, at Cheeka Peak Observatory (CPO), located on the tip of the Olympic Peninsula, Washington State. This sampling campaign was in conjunction with the 2002 Inter-Continental Transport and Chemical Transformation (ITCT 2K2) Campaign and the Photochemical Ozone...
The use of semi-volatile organic compounds (SOCs) as molecular markers to identify the contributions of regional and long-range atmospheric transport, as well as current and historic sources, and contaminant deposition in remote ecosystems of the Western U.S. was investigated. Trans-Pacific air masses influenced by Siberian biomass burning events had elevated...
This study investigates the relationship between total and ionic copper in samples taken from the Tualatin River and wastewater treatment facilities (WWTFs) that discharge into the Tualatin River. Copper speciation was analyzed by determining conditional stability constants and densities of copper binding ligands on the dissolved organic matter (DOM) in...