The environment has been exposed to a number of hazardous chlorinated
organic compounds. These compounds may be anaerobically biotransformed by
sequential reductive dechlorination reactions in which the chlorine atoms are
replaced with hydrogen atoms. Because reductive dechlorination processes may
occur very slowly in the environment and chlorine position affects the...
Food habits and levels of organochlorine compounds, lead, and mercury in resident and wintering bald eagles were studied in southcentral Oregon and California, 1979-83. Food habits were assessed by examination of castings from winter communal roosts, identification of 2938 prey items found at nest sites and foraging areas, and observations...
Effective methods for the enantiopure formation of substituted piperidine rings are significantly important due to their presence in alkaloid products. A valuable method to form these ring systems would be via an intramolecular heteroatom Michael addition from the corresponding enone or enal. Described herein is a methodolgy that has been...
Ambifunctional axially chiral 2,2',6,6'-tetrasubstituted biphenyls containing nucleophilic (or basic) functional groups juxtaposed with hydrogen-bond donors were synthesized and their properties studied. Applications for the prepared biaryls as potential organocatalysts for enantioselective carbon-carbon bond forming reactions were examined. Processes investigated included: aldol, Michael, nitroaldol (Henry), and Baylis-Hillman reactions.
The novel amidoamine...