Index Catalog // ScholarsArchive@OSU

Creator:: Miller, Jeffrey Templeton
Abstract:: I. Lithium alkyl and aryl monosubstituted cyclooctatetraenide dianions (Li₂ C₈H₇-R; R = methyl, n- butyl, sec- butyl, tert- butyl, phenyl and benzyl) were synthesized by the reaction of the appropriate organolithium reagent with cyclooctatetraene in diethyl ether or tetrahydrofuran. The reaction occurred cleanly and with good yield of lithium monosubstituted...
Resource Type:: Dissertation
Full Text:: . Uranocene is the only organometallic compound known to react with nitrobenzene yielding azobenzene and

Creator:: Brault, Margaret A.
Resource Type:: Dissertation
Full Text:: COT with Yb metal atoms yielded the known compound Yb(C8H8). The infrared spectra of these complexes

Creator:: Emerson, Christopher R.
Abstract:: Sulfoxide-ligand exchange (SLE) and asymmetric halogen-metal exchange (AHME) processes were separately examined for the enantioselective synthesis of functionalized alpha-haloalkylmetal (carbenoid) reagents. Carbenoids derived from SLE were used to effect stereospecific reagent-controlled homologation (StReCH) of boronic esters and those generated via AHME were engaged in Darzens-type chemistry with aldehydes. Abstract for...
Resource Type:: Dissertation
Full Text:: )cyclohex-4-ene (6 steps, 5% overall yield); the non- deuterated isotopomer of this compound was previously

Creator:: Maack, Bryan A.
Abstract:: Metal-organic frameworks (MOFs) represent an exciting, new class of porous materials. Their hybrid organic-inorganic structure opens up near infinite possibilities to tune and design their structure for specific properties and applications. A new generation of flexible MOFs, following a generation of stiff MOFs, has created additional design space and complexity....
Resource Type:: Masters Thesis

Creator:: Li, Yong J.
Abstract:: Metal Organic Framework (MOF) materials, consisting of metal ions with organic linkers, have a functional cavity structure which can be utilized in applications such as catalyst, micro sensing, and gas absorption. Due to MOF materials' selective gas adsorption property, interest in MOF materials has intensified in the last few years,...
Resource Type:: Masters Thesis
Full Text:: bonding and symmetry of the molecule can be identified through the vibration of the compound using Raman

Creator:: Ma, Guoheng
Abstract:: Transparent and electrically conductive metal oxide nanoparticles have attracted much attention, and can be used to improve the performance of solar cells, transparent electrode materials, and gas sensor technology. Specifically, indium tin oxide (ITO) nanocrystals (NCs) are potentially useful nanomaterials, having technological applications in enhanced sensitivity of optical spectroscopy due...
Resource Type:: Masters Thesis
Full Text:: the hydrolysis reactions of organometallic compounds and metal-surfactant complexes in hot

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