A new approach towards a total synthesis of paeoniflorigenin is discussed. The approach involves the application of regio- and stereoselective [2+2] photocycloaddition for the preparation of a key intermediate, cyclobutanone 86, and model studies on diiodosamarium (Sm12) mediated pinacol coupling of a diketone. Intermolecular [2+2] photocycloaddition of a,13unsaturated lactam 33...
Lycopodium alkaloids have generated enormous amounts of interest from the scientific community, both as synthetic targets and for their medicinal properties. Herein is described work towards a unifying approach to large segments of the Lycopodium family. An organocatalyzed intramolecular heteroatom Michael reaction method, for the construction of piperidine and piperizine...
Many non-native weed pests of food, fiber, and nursery crops pose threats to U.S. environment and agriculture. Noxious weed regulations play an important role in preventing the introduction and spread of non-native plants, thereby protecting the local biodiversity, environment and economic activities. However, these regulations could also hamper agricultural trade....
Coal power is the prominent source of energy in the United States (U.S.) and around the world. The byproducts of coal power contain many of the same radioactive nuclides that are found in the local environment just in higher concentrations. With so much of this ash being stockpiled, the amount...
The objectives of this study were to evaluate the physicochemical properties and bioactive compounds from four different types of fruit pomace, including apple, blueberry, raspberry, and cranberry, and further to investigate the feasibility of creating apple pomace based biocomposite boards using thermal compression molding and to optimize the biocomposite formulations...
Quarantines and control programs are two policy tools used to prevent and reduce the damages caused by invasive species. Quarantines restrict the movement of material that could spread invasive species. Their requirements impose costs on businesses within the quarantine zone by creating barriers to trade and increasing production costs, which...
Oregon's nursery and greenhouse industry has ranked the first in the State's agricultural for 18 years. The majority of nursery sales from the Pacific Northwest come from Oregon. Due to data limitations, empirical study of the Oregon nursery industry is rare. The present dissertation consists of three essays that analyze...