Polybenzimidazoles were synthesized from 3, 3', 4, 4'-tetraminobiphenyl
(diaminobenzidine, or DAB) with orthoesters, carboxylic acid derivatives (an ester and
an acid) and with m-benzenedialdehyde. The products were of low molecular weight,
as evidenced by low inherent viscosity, except in the case of the dialdehyde plus DAB.
The product of that...
Described herein is the synthesis of an uncharged stereoregular oligonucleotide
analog consisting of cytosine bases linked at specific intervals to a polyamide backbone
derived from (L)-glutamic acid. Preparation of this analog entailed borane reduction of
(L)- pyroglutamic acid to give optically pure lactam alcohol 9. Tosylation and alkylation
with cytosine...
Polybenzimidazoles were synthesized from 3,3'-diaminobenzidine (DAB) and dicarboxylic acids. The polymerizations using the dicarboxylic acid monomers were carried out in polyphosphoric acid (PPA) and phosphorus pentoxide/methansulfonic acid (PPMA) which acted as the solvent and condensing agent. The resulting polybenzimidazoles had inherent viscosities in the range of 0.12 to 0.84 dL/g....
Polymer samples of polytetrafluoroethylene (PTFE) and a PTFE-glass weave (RF- 35P) are exposed to low pressure, non-equilibrium glow discharge plasmas for enhanced wettability as measured by static contact angles. Plasma treatments are performed in two parallel plate RF plasma systems, a downstream microwave plasma and a barrel etcher using feed...
Equal molar amounts of (+)-catechin and N-Hydroxymethylacetamide
were reacted under acidic conditions. Thin-layer
chromatography (TLC) was used to monitor the reaction.
The reaction products were isolated by column chromatography
using Sephadex LH-20 and elution with 95 percent ethanol.
Three reaction products isolated included one
disubstituted and two monosubstituted compounds. The...
