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Possible paths for the alpha blocked dienone-phenol rearrangement

Creator:: Magoon, Eugene Franklin
Resource Type:: Dissertation
Full Text:: Rearrangement POSSIBLE PATHS FOR THE ALPHA BLOCKED DIENONE-PBENOL REARRANGEMEIT by EUGENE FRANKLIN

The rearrangement of 1, 1-dimethyl-2-oxo-1, 2-dihydronaphthalene

Creator:: Stephenson, John Louis
Resource Type:: Masters Thesis
Full Text:: The Rearrangement of 1,1-Dimethyl-2-Oxo-1,2

The rearrangement of the side chain of N-propylbenzene under electrophilic substitution conditions

Creator:: Huff, Richard Royce
Resource Type:: Masters Thesis
Full Text:: The rearrangement of the side chain of N-propylbenzene

Concerted dearomatization reactions : cis-1-phenyl-2-vinylcyclopropane in the Cope rearrangement

Creator:: Lin, Crystal
Resource Type:: Dissertation
Full Text:: -cyclopropane in the Cope Rearrangement AN ABSTRACT OF THE THESIS OF CRYSTAL LIN (Name) for the degree

Siloxy-cope rearrangements of the trans-l-vinylcyclotridec-3-en-l-ol system

Creator:: Bolesta, Richard Edward
Abstract:: The thermolysis of trans-1 -trimethylsiloxy- 1-vinylcyclotridec- 3-ene (VI-OTMS) led to the formation of two major products: 4-vinylcyclotridecanone (VII) and cyclopentadec-5-en-l-one (VIII) after hydrolysis. Ketone VII is produced by a concerted [3, 3] sigmatropic shift, while ketone VIII is formed by a [1, 3] sigmatropic shift with a concerted or diradical...
Resource Type:: Masters Thesis
Full Text:: degree of Master of Science in Chemistry (Organic) presented on Title: SILOXY-COPE REARRANGEMENTS OF

Catalytic rearrangement of cyclodeca-1,2,5-triene and oxymercuration of bicyclo-[7.1.0]-deca-2,3-diene

Creator:: Boop, Janice Lee
Abstract:: The reaction of cyclodeca-1,215triene with mercuric salts gave only rearranged hydrocarbon, tricyclo[4.4.0.0²'⁴]deca-5ene in acetic acid. Other catalysts [Rh(CO)₂C1]₂ and AgC10₄ gave the same rearranged hydrocarbon. The isomerization is proposed to proceed through a "metalcomplexed" carbenoid intermediate. The reaction of bicyclo[7.1.0 ]deca-213diene gave oxymercurated products.
Resource Type:: Masters Thesis
Full Text:: Catalytic rearrangement of cyclodeca-1,2,5-triene and

Thermal [pi]-route rearrangement of 4-cycloheptane-1-methyl acetate

Creator:: Schick, Lawrence Edward
Abstract:: Pyrolysis of 4-cycloheptene-l-methyl acetate under flow conditions at 285° gives only rearranged bicyclic acetates and hydrocarbons rather than the anticipated simple elimination product methylenecyclohept- 4-ene. These rearranged acetates have the same structures and are formed in virtually the same relative percentages as those observed in the "π- route" solvolysis of...
Resource Type:: Dissertation
Full Text:: Philosophy in Chemistry (Organic) presented on /--/LAP-4, Az=7 Title: Thermal II- Route Rearrangement of 4

Substituent control in the oxy-Cope rearrangements of 1-vinyl-trans-cyclotridec-3-en-1-ol systems

Creator:: Daruwala, Khushroo Peshotan
Abstract:: The thermal and anionic rearrangements of substituted 1-vinyltrans- cyclotridec-3-en-l-ol compounds have been studied to determine what effects substituents would have on the sigmatropic shift when placed on the two positions of the 1-vinyl group. For the thermal rearrangements, the a-substituted vinyl-trans-cyclotridecenols gave both the [3,3] and [1,3] shift products of...
Resource Type:: Dissertation
Full Text:: his allylsilane chemistry to set up a substrate for an oxy-Cope rearrangement.2° Scheme 25 OH KH

Studies in the pinacol-pinacolone rearrangement

Creator:: Mosher, Harry S.
Abstract:: The synthesis of 3,3'-diphenylbenzopinacol was carried out both by means of the Grignard reaction between m-diphenyl magnesium iodide and benzil, and by reduction of m-phenyl benzophenone. The pinacol was rearranged and the products analyzed. The migration aptitude of m-biphenyl was determined to be 1.5. Attempts to prepare 3,3'-diphenyl-4,4'-dimethylbenzopinacol were unsuccessful....
Resource Type:: Masters Thesis

Kinetic studies of some thermal rearrangements

Creator:: Schatz, Bruce Stewart
Resource Type:: Dissertation
Full Text:: ABSTRACT OF THE THESIS OF Bruce Stewart Schatz for the Ph. D. in Chemistry (Name) (Degree) (Major

ScholarsArchive@OSU

Possible paths for the alpha blocked dienone-phenol rearrangement

The rearrangement of 1, 1-dimethyl-2-oxo-1, 2-dihydronaphthalene

The rearrangement of the side chain of N-propylbenzene under electrophilic substitution conditions

Concerted dearomatization reactions : cis-1-phenyl-2-vinylcyclopropane in the Cope rearrangement

Siloxy-cope rearrangements of the trans-l-vinylcyclotridec-3-en-l-ol system

Catalytic rearrangement of cyclodeca-1,2,5-triene and oxymercuration of bicyclo-[7.1.0]-deca-2,3-diene

Thermal [pi]-route rearrangement of 4-cycloheptane-1-methyl acetate

Substituent control in the oxy-Cope rearrangements of 1-vinyl-trans-cyclotridec-3-en-1-ol systems

Studies in the pinacol-pinacolone rearrangement

Kinetic studies of some thermal rearrangements

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