Most authigenic carbonates previously recovered from the Cascadia slope have Sr-⁸⁷/Sr-⁸⁶ signatures that reflect shallow precipitation in equilibrium with coeval seawater. There is also evidence for carbonate formation supported by fluids that have been modified by reactions with the incoming Juan de Fuca plate (Sr-⁸⁷/⁸⁶(Sr) = 0.7071; Teichert et al.,...
We present a new method developed for measuring radiocarbon of methane (¹⁴CH₄) in ancient air samples
extracted from glacial ice and dating 11,000–15,000 calendar years before present. The small size (~20 μg CH₄ carbon), low
CH₄ concentrations ([CH₄], 400–800 parts per billion [ppb]), high carbon monoxide concentrations ([CO]), and low...