Since the discovery of molecular chirality in 1848, this notion has had a substantial impact on medicine, biology, and chemistry. Extensive effort has been directed towards the construction of chiral molecules that contain sp³ hybridized stereogenic centers. In contrast, less effort has been dedicated to molecules that are chiral by...
Restricted rotations of chemical bonds can lead to the presence of persistent conformational chirality in molecules 10 lacking stereocenters. We report the development of first-ofa- kind predictive rules that enable identification of conformational chirality and prediction of racemization barriers in the diarylether heptanoid (DAEH) natural products that do not possess...
Lactic streptococcal agglutinins are known to promote settling of starter bacteria in milk, resulting in spongy, mealy, shattered curd and sludge formation defects in cottage cheese. These agglutinins are natural antibodies secreted by lactating cows in mature milk in response to infections (mastitis) and in colostrum milk as protective antibodies...
The ability of Propionibacterium shermanii to produce
growth metabolites which were inhibitory to food spoilage
indicator organisms was investigated. Asperqillus niqer,
a Pseudomonas species and Kluyveromyces fraqilis were the
spoilage indicators chosen to represent molds, gram
negative psychrotrophic bacteria and yeasts, respectively.
Supplementation of milk or whey based media was...
To increase efficiency of seed production, it is important to
understand the effects of nitrogen (N) fertilizer rate and time of
application. In particular, the effects on floret fertility should
be examined since only a small proportion of florets actually produce harvestable seed. For these reasons, experiments were conducted in...
Wheat is an important cereal crop in the Willamette Valley of
Oregon and the stiff-strawed, high yielding winter varieties are
the predominate types grown although spring varieties are not uncommon.
Because of the mild, often open winters; present in the
Willamette, it is not unusual to be able to seed...
Aminal radical intermediates were generated by the method of radical translocation and reacted in C-C bond forming reactions with electronically deficient alkenes (Schiedler et al. Org. Lett. 2012, 14, 6092). Aminal radical intermediates can participate in inter- and intra-molecular reactions using both Bu3SnH and (TMS)₃SiH as hydride donors. Carbon–carbon bonds...
Complex organic transformations, such as the addition of pyrrole to ketene using planar chiral organocatalyst (*PPY), the four-component anhydride- Manniach reactions, and the site-selective desymmetrization of meso-1,2-diol, are remarkable synthetic reactions that provide high yield and high selectivity. However, the exact mechanism and origins of stereocontrol for theses synthetic organic...