Nitrogen (N) is the most important nutrient to manage in the overall wine production system, since N has a large influence on vine productivity and fruit quality in the vineyard and also on fermentation kinetics and fermentation-derived aromas in the winery. Previous studies investigated the influence of either vineyard N...
It is estimated that 50-75% of Oregon vineyards cultivate at least every other alley in order to 1) reduce water stress 2) increase vineyard canopy temperatures and 3) increase nutrient availability. Because many vineyards are situated on steep hillsides, frequent tillage could result in increased soil erosion, decreased soil quality...
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R. PaulSchreiner
It is estimated that 50-75% of Oregon vineyards cultivate at least
Resident and migratory avifauna in the Willamette Valley, Oregon are heavily influenced by winter conditions and habitat characteristics, especially those of wetlands. As such, it is important to monitor avian communities and environmental factors at wetland sites within the Willamette Valley during winter. Using data from standardized avian point-count surveys,...
The bimolecular reaction of two carbenoid species resulting in the formation of a carbon-carbon double bond (pi-system), referred to herein as carbenoid eliminative cross-coupling (CEXC), involves a series of three fundamental steps: (i) ate-complex formation (transmetalation), (ii) 1,2-metalate rearrangement, and (iii) beta-elimination. All three steps are stereospecific and so the...
Chalaniline A, an unusual xanthone-like aminofulvene with modest cytotoxicity, and chalaniline B [1-anilino-2,8-dihydroxy-3-(hydroxymethyl)xanthone], an antibacterial aminoxanthone, were previously isolated by Loesgen and coworkers from vorinostat-treated Chalara sp. 6661. Of note, the anilino moiety found within both chalaniline structures originates from biotransformation of the HDAC inhibitor vorinostat (SAHA, suberanilohydroxamic acid) by...
Xanthohumol [XN, (E)-6´-methoxy-3´-(3-methylbuten-2-yl)-2´,4´,4´´-trihydroxychalcone], the principal prenylated chalcone from hops, and its 2,3-dihydro- (DXN) and O6-desmethyl-2,3-dihydro- (DDXN) congeners, are of potential utility for the amelioration of metabolic syndrome; however, their complex bioactivity profiles cannot be properly studied and understood without access to appropriately produced synthetic materials.
In the first part of...
Traditional approaches for the direct preparation of alkenes are unable to fully control either the stereochemical configuration of the carbon-carbon double bond or else the regiochemistry of the substituents surrounding it. The recently introduced concept of carbenoid eliminative cross-coupling (CEXC) offers a remedy to these deficiencies by providing for a...
Due to threats of secondary salinization caused by increased saltwater intrusion upstream associated with climate change, this thesis examines how salinity affects the development and oviposition site selection habits of three Oregon coastal breeding amphibians, the Roughskin Newt (Taricha granulosa), the Northern Red-legged Frog (Rana aurora) and the Pacific Treefrog...
In Part I, (4S,5R)-4,5-dimethyl-4-phenylcyclohex-2-enone (19a) was prepared in 73% yield with high enantio- and diastereo-selectivity (er > 98:2, dr > 20:1) on a multigram scale by a Yamada-Otani condensation between (E)-pent-3-en-2-one and 2-phenylpropanal catalyzed by a sulfonimide derivative of (S)-proline (18, HuaCat®). Synthetically useful transformations of the cyclohexenone product 19a...
Three distinct methods to achieve the stereoselective synthesis of carbon-carbon bonds were investigated, encompassing: (i) the formation of axially chiral biaryl molecules by enantioselective Suzuki cross-coupling, (ii) the synthesis of α-phenylalkylboronic esters by enantioselective chain extension, and (iii) the stereospecific synthesis of alkenes by eliminative cross-coupling of enantioenriched sp³-hybridized carbenoids....