Aminal radical intermediates were generated by the method of radical translocation and reacted in C-C bond forming reactions with electronically deficient alkenes (Schiedler et al. Org. Lett. 2012, 14, 6092). Aminal radical intermediates can participate in inter- and intra-molecular reactions using both Bu3SnH and (TMS)₃SiH as hydride donors. Carbon–carbon bonds...
The aspidosperma alkaloid goniomitine was synthesized in six steps from 2-ethyl-δ-valerolactam. The convergent strategy features an Ullman coupling to assemble the required carbon atoms. A complexity-generating radical translocation reaction was used to build the indole architecture.
Background:
There are over four billion YouTube views per day with “music” the most searched topic. Among US internet users, 8.3 million YouTube users are under 18 years old. Incorporation of substance use imagery in YouTube videos has a considerable potential influence on young viewing audience behavior. This study identifies...
Mesoscale fronts occur frequently in many coastal areas and often are sites of elevated
productivity; however, knowledge of the fine-scale distribution of zooplankton at these
fronts is lacking, particularly within the mid-trophic levels. Furthermore, small (<13 cm) gelatinous
zooplankton are ubiquitous, but are under-studied, and their abundances underestimated
due to...
Full Text:
zooplankton community
across a mesoscale front
Jessica Y. Luo1,*, Benjamin Grassian1, Dorothy Tang1, Jean
Mesoscale fronts occur frequently in many coastal areas and often are sites of elevated
productivity; however, knowledge of the fine-scale distribution of zooplankton at these
fronts is lacking, particularly within the mid-trophic levels. Furthermore, small (<13 cm) gelatinous
zooplankton are ubiquitous, but are under-studied, and their abundances underestimated
due to...
Full Text:
front
Jessica Y. Luo1,*, Benjamin Grassian1, Dorothy Tang1, Jean-Olivier Irisson2,
Adam T. Greer1,3
Mesoscale fronts occur frequently in many coastal areas and often are sites of elevated productivity; however, knowledge of the fine-scale distribution of zooplankton at these fronts is lacking, particularly within the mid-trophic levels. Furthermore, small (<13 cm) gelatinous zooplankton are ubiquitous, but are under-studied, and their abundances underestimated due to...
conservation and ecology. Currently, the most widely used methods for obtaining such estimates involve either sighting
animals from transect lines or some form of capture-recapture on marked or uniquely identifiable individuals. However,
many species are difficult to sight, and cannot be easily marked or recaptured. Some of these species produce...
Genomic instability drives tumorigenesis, but how it is initiated in sporadic neoplasias is unknown. In early preneoplasias, alterations at chromosome fragile sites arise due to DNA replication stress. A frequent, perhaps earliest, genetic alteration in preneoplasias is deletion within the fragile FRA3B/FHIT locus, leading to loss of Fhit protein expression....
Ecohydrological connectivity is a system level property that results from the linkages in the networks of water transport through ecosystems, by which feedbacks and other emergent system behaviours may be generated. We created a system dynamics model that represents primary ecohydrological networks to examine how connectivity between ecosystem components impacts...
In 2006, a marked increase in harbor porpoise Phocoena phocoena strandings were reported in the Pacific Northwest of the USA, resulting in the declaration of an unusual mortality event (UME) for Washington and Oregon to facilitate investigation into potential causes. The UME was in place during all of 2006 and...