One common assumption in interpreting ice-core CO₂ records is that diffusion in the ice does not affect the concentration profile. However, this assumption remains untested because the extremely small CO₂ diffusion coefficient in ice has not been accurately determined in the laboratory. In this study we take advantage of high...
We have measured the CO₂ concentration of air occluded during the last 40,000 years in the deep Siple Dome A (hereafter Siple Dome) ice core, Antarctica. The general trend of CO₂ concentration from Siple Dome ice follows the temperature inferred from the isotopic composition of the ice and is mostly...
We undertook an interlaboratory comparison of techniques used to extract and analyze trapped gases in ice cores. The intercomparison included analyses of standard reference gases and samples of ice from the Greenland Ice Sheet Project 2 (GISP2) site. Concentrations of CO₂, CH₄, the δ¹⁸O of O₂, the δ¹⁵N of N₂,...