The Gd3+ ion has been used to induce quantum splitting in luminescent
materials by using cross-relaxation energy transfer (CRET). In Nd:LiGdF4, quantum
splitting results from a two-step CRET between Gd3+ and Nd3+, first involving a
transition 6G→6I on Gd3+ and an excitation within the 4f3 configuration of Nd3+
followed by...
Calcium alginate gels are widely used in the biotechnology, food, and pharmaceutical industries for cell immobilization, food additives, and controlling the release of therapeutic agents. Different gelation conditions can lead to different gel structures which affects the diffusion of solutes in gels, thus mathematical models were developed to describe diffusion...
Gallium arsenide shows excellent promise for terahertz generation using mid infrared.
This is for two reasons. First, the indices of refraction for the terahertz (nTHz=3.61 at 1 THz) and mid infrared (nopt=3.431 at 2 μm) are close allowing a long interaction length.
Second, the linear absorption is low at terahertz...
In this thesis I studied several THz components that can be used for potential THz
technology. THz waves were generated in nonlinear medium via optical rectification
of femtosecond optical pulses. Utilizing the phase matching condition between the
optical and THz waves in a ZnTe crystal, single-cycle broad-band THz pulses were...
Immersion energies for an impurity in a homogeneous electron gas with a uniform positive background charge density have been calculated numerically using density functional theory. The numerical aspects of this problem are very demanding and have not been properly discussed in previous work. The numerical problems are related to approximations...
An expedient approach to the synthesis of a wide range of highly programmable biaryl templates has been accomplished. Utilizing the Diels-Alder [4+2] cycloaddition, a wide range of tri- and tetra-ortho-substituted biaryls have been synthesized in only three to four steps from commercially available materials. We have successfully synthesized entire classes...
The extended-Lifshitz-Kosevitch formalism (ELK) unifies the treatment of
the de Haas-van Alphen (dHvA) effect, allowing it to transcend its traditional roles
of mapping Fermi surfaces and measuring effective masses. Here we exploit the
capabilities of dHvA as a probe of many-body effects to examine heavy-fermion su-
perconductivity. ELK successfully describes...