The electrochemistry of cadmium at a Reticulated Vitreous
Carbon (RVC) electrode has been studied to determine the suitability of
RVC as a working electrode for the electrochemical preconcentration of
cadmium in the corrosive environment of zirconium dissolved in
hydrofluoric acid.
The electrochemistry in this investigation deals with deposition
of solid...
The oxide/electrolyte solution interface has been studied experimentally by two methods, and a mathematical model for the interface has been developed. The change in interfacial potential with solution composition was determined through the capacitance of electrolyte/oxide/semiconductor (EOS) structures and the charge through potentiometric titrations of colloidal oxide suspensions. The differential...
The distribution of hydrophobic ionogenic organic compounds
(HIOC's) between aqueous and nonaqueous phases has been
investigated. The HIOC's are aniline and methyl substituted
anilines. The aqueous phases are methanol-water mixed solvents with
varying pH and ionic strength. The nonaqueous phases are silica and
alkyl derivatized silica with ethyl- (C-2), octyl-...
An analytical technique has been developed for the determination of methylmercury
compounds in environmental samples. The technique is based on a two-stage procedure.
In the first stage, methylmercury compounds are isolated from the sample matrix as
methylmercury chloride (MeRgCl) by distillation. The distillation procedure is based on a
series of...
Contaminant transport in ground water is an important environmental process that
affects a host of natural systems. Transport of contaminants is affected by many
processes, including aqueous complexation, adsorption, and redox reactions. One of the
most important components of an aquifer that controls transport is iron-oxide. In this
study, the...
Evaporative loss rates of pesticides, following application to turfgrass, were measured using the Backward-Time Lagrangian stochastic Dispersion model (Flesch, Wilson, Journal of Applied Meteorology, 34, pp. 1320-1332. All pesticides were applied to a 22.8 m x 22.8 m orchard ryegrass turf plot near Corvallis, Oregon. Solar radiation, ambient temperature, surface...