It is difficult to relate intrinsic nanomaterial properties to their functional behavior in the environment. Unlike frameworks for dissolved organic chemicals, there are few frameworks comparing multiple and inter-related properties of engineered nanomaterials (ENMs) to their fate, exposure, and hazard in environmental systems. We developed and evaluated reproducibility and inter-correlation...
Both nanoparticulate (nZnO and nTiO(2)) and organic chemical ultraviolet (UV) filters are active ingredients in sunscreen and protect against skin cancer, but limited research exists on the environmental effects of sunscreen release into aquatic systems. To examine the trade-offs of incorporating nano particles (NPs) into sunscreens over the past two...
Sulfoxide-ligand exchange (SLE) and asymmetric halogen-metal exchange (AHME) processes were separately examined for the enantioselective synthesis of functionalized alpha-haloalkylmetal (carbenoid) reagents. Carbenoids derived from SLE were used to effect stereospecific reagent-controlled homologation (StReCH) of boronic esters and those generated via AHME were engaged in Darzens-type chemistry with aldehydes.
Abstract for...
The adsorption of natural organic matter (NOM) to the surfaces of natural colloids
and engineered nanoparticles is known to strongly influence, and in some cases control,
their surface properties and aggregation behavior. As a result, the understanding of
nanoparticle fate, transport and toxicity in natural systems must include a fundamental...
Climate change remains controversial and misunderstood, despite the consensus among climate scientists that recent climate change is anthropogenic. Many American adults do not agree with or do not understand this scientific consensus, suggesting a disconnect in science communication or a distrust in science. This disconnect may begin in formal education...
Nanoparticles are becoming increasingly important in numerous technological fields but evidence shows that they can be toxic to many organisms. To predict their fate and transport in the environment, nanoparticle attachment to naturally occurring colloids must be examined. This study investigated citrate-capped gold nanoparticle (Cit-AuNP) heteroaggregation with two model colloids...
Addiction is a word that represents a condition that, at best, causes minor disruptions to one’s life and, at worst, is lethal. The current definition was developed by 80 neuroscientists. It references substance use and other behaviors and includes food and sex. Addictions do not seem to be lessening but...
Coral reefs are in decline worldwide, and land-derived sources of pollution, including sewage, are a major force driving that deterioration. This review presents evidence that sewage discharge occurs in waters surrounding at least 104 of 112 reef geographies. Studies often refer to sewage as a single stressor. However, we show...
The chemolithoautotrophic nitrite oxidizing bacteria (NOB) participate in the
biogeochemical cycling of nitrogen by catalyzing and conserving energy from the
oxidation of nitrite (NO₂-) to nitrate (NO₃-) via a nitrite oxidoreductase (NXR). The
main objective of this work was to comparatively annotate and analyze the genome
sequences of Nitrobacter winogradskyi...
The Columbia River Treaty (CRT) is often used as an example of how treaties can work to normalize, regulate, and improve the cooperative management of shared water resources between basin countries. Few would argue that, in its limited mandate to regulate hydropower generation and flood risk management for downstream communities,...