Thin films of the p-type semiconductor, barium copper sulfide fluoride (BaCuSF) were deposited using pulsed laser deposition. Similar p-type conductivity in Cu2O is caused by copper vacancies. Addition of copper dopant is proposed as a method for filling the copper vacancies in BaCuSF. The films are characterized to determine quality...
BaCuChF (Ch = S, Se, Te) materials are chalcogen-based transparent conductors with wide optical band gaps (2.9 – 3.5 eV) and a high concentration of free holes (10¹⁸ – 10²⁰ cm⁻³) caused by the presence of copper vacancies. Chalcogen vacancies compensate copper vacancies in these materials, setting the Fermi level...
A stable-isotope stratigraphy at Site 846 (tropical Pacific, 3°06'S, 90°49'W, 3307 m water depth), based on the benthic
foraminifers Cibicides wuellerstorfi and Uvigerina peregrina, yields a high-resolution record of deep-sea δ¹⁸O and δ¹³C over the
past 1.8 Ma, with an average sampling interval of 3 k.y. Variance in the δ¹⁸O...
Native point defects, defect complexes, and oxygen impurities in BaCuChF were studied using density
functional theory calculations, self-consistent thermodynamic simulations, and various experimental techniques.
Unintentional p-type conductivity in BaCuChF is explained by the presence of copper vacancies with
transition levels in the valence band. These acceptor-like defects are partially compensated...
High-temperature combustion oxidation measurements of nonvolatile dissolved organic carbon (DOC) have been determined for pore waters from sediments of Middle Valley, Ocean Drilling Program Leg 139, as well as for overlying and near-bottom seawater. The DOC values in the interstitial waters are generally greater than those in the overlying water...
Sediments from five Leg 167 drill sites and three piston cores were analyzed for C[subscript ORG] and CaCO₃. Oxygen isotope stratigraphy on benthic foraminifers was used to assign age models to these sedimentary records. We find that the northern and central California margin is characterized by k.y.-scale events that can...
The sorbed gases at all four Ocean Drilling Program Leg 139 sites (855, 856, 857, and 858) showed the unmistakable presence of thermogenic hydrocarbons. No indication of abiogenic gas was found. The evidence for the thermogenic hydrocarbons includes elevated contents of higher hydrocarbons (i.e., C₁/[C₂ + C₃] ca. 2-20), δ¹³CCH₄...
The accelerated diagenesis, maturation, and catagenesis of organic matter to hydrothermal petroleum was studied in sediments from Ocean Drilling Program Leg 139 in Middle Valley, northern Juan de Fuca Ridge. Sediments at Sites 855 and 856 have experienced high heat flow resulting in accelerated diagenesis of the immature organic matter...
Billions of pounds of bisphenol A (BPA) are produced annually around the globe for the manufacture of numerous consumer products, including polycarbonate food and water containers, the protective resin linings of food cans, thermal printing paper, and dental fillings. BPA exposure during nervous system development has been associated with learning...
In shallow water, any two waves of the same frequency are shown to produce complex patterns of
drift velocity above the sea bed. If the longshore components λ₁, λ₂ of the wave numbers of the two
waves are different, these steady flow patterns exhibit a longshore periodicity of wave number...