A Bulk Metallic Glass (BMG) is an amorphous solid with thickness greater than 1mm. Material properties of BMG, like twice the strength of regular steels and excellent corrosion resistance, make them ideal materials for fabrication of MEMS and MECS devices which have attracted a lot of research activity recently. Diffusion...
Zirconium press plates have been developed for the production of melamine coated particle board, using shot-peening to achieve the desired plate (and therefore coated particle board) surface texture. Service temperatures of the press plates approach 200°C. This study examined the microstructural effects of extended exposure of shot-peened zirconium to temperatures...
By the investigation of the bulk metallic glass-forming liquids that have very low critical cooling rates, the thermodynamics of metallic glasses can be clarified. For studying thermodynamic properties, such as the specific heat capacity, calorimetry (DSC) is utilized and one of the most used instruments is the differential scanning calorimeter....
The heating rate dependence of the glass transition temperature of the
Ni₆₅Nb₃₅, Ni₆₀Nb₃₅Sn₅, Ni₅₉.₃₅Nb₃₄.₄₅Sn62, Ni₆₀(Nb₄₀Ta₆₀)₃₄Sn₆, and
Ni₅₇Fe₃Nb₃₅Sn₅ metallic glass forming alloys was investigated with a
differential scanning calorimeter (DSC). The inverse heating rate for each
DSC experiment was plotted versus inverse temperature and a Vogel-Fulcher-
Tamman (VFT) type relation was...
Among recently found multi-component Zr-based bulk metallic glasses (BMG), Zr₅₈.₅Cu₁₅.₆Ni₁₂.₈Al₁₀.₃Nb₂.₈ is characterized by its lower critical cooling rate requirement and absence of beryllium as one of the constituent element which makes its handling more convenient. Its large supercooled liquid regions made possible the study of thermodynamics and kinetics of this...
In order to achieve a better understanding of the processes that occur during
formation and sintering of zirconia, various chemical and physical techniques were
used. Along with Perturbation Angular Correlation spectroscopy, that allowed us to
investigate microscopic properties inside the nanometer-size zirconia grains, such
techniques as Scanning Electron Microscopy and...
A high temperature high vacuum rheometer has been designed, fabricated,
and tested for the study of the steady shear viscosity for multicomponent bulk
metallic glass forming alloys. This rheometer has an operating range up to
1525 K, rotational frequencies of 9.4*10⁻³-3.7*10¹ radians/s, and a
calibrated viscosity range of 9.6*10⁻³ and...
Ti-6Al-2Sn-4Zr-2Mo-0.1Si specimens were shaped by repeated cycles of heating
(to 954 °C) and hammer or press forging followed by a solution anneal that varied from
968 to 998 °C. The coupons were originally extracted from billets forged below the beta
trans us ( 1009 °C) and slow cooled to ambient...
Experimental data on the structural phase changes in zirconia are summarized. The computational techniques of molecular dynamics are reviewed and equations of motion are formulated which allow the study of phase changes as a function of temperature and pressure. The molecular dynamics program NPT which was written for this purpose...