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https://ir.library.oregonstate.edu/concern/articles/2r36v0354

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  • Porous silicon prepared by low-cost and scalable magnesiothermic reactions is a promising anode material for Li-ion batteries; yet, retaining good cycling stability for such materials in electrodes of practical loading remains a challenge. Here, we engineered the nanoporous silicon from a modified magnesiothermic reaction by controlled surface oxidization forming a <5 nm oxide layer on the 10–20 nm Si nanocrystallites. High loading electrodes of ~3 mAh/cm² demonstrates stable cycling with ~80% capacity retention over 150 cycles. The specific discharge capacity based on the total electrode weight is ~1000 mAh/g at the lithiation/delithiation current density of 0.5/0.75 mA/cm². This work reveals the importance of the surface treatment on nanostructured Si, which will lead to a well-controlled ratio of silicon and surface oxide layer and provide guidance on further improvement on silicon-based anode materials.
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  • description.provenance : Made available in DSpace on 2016-03-16T15:04:10Z (GMT). No. of bitstreams: 2 LiStableNanoporousSilicon.pdf: 3909833 bytes, checksum: 5255c0f044736afaf2aa6ad052f7d040 (MD5) LiStableNanoporousSiliconSupplementFigureS1-S3.pdf: 409282 bytes, checksum: d02612ef153d85f5d449bfd87c452d49 (MD5) Previous issue date: 2016-02
  • description.provenance : Submitted by Patricia Black (patricia.black@oregonstate.edu) on 2016-03-16T15:03:44Z No. of bitstreams: 2 LiStableNanoporousSilicon.pdf: 3909833 bytes, checksum: 5255c0f044736afaf2aa6ad052f7d040 (MD5) LiStableNanoporousSiliconSupplementFigureS1-S3.pdf: 409282 bytes, checksum: d02612ef153d85f5d449bfd87c452d49 (MD5)
  • description.provenance : Approved for entry into archive by Patricia Black(patricia.black@oregonstate.edu) on 2016-03-16T15:04:10Z (GMT) No. of bitstreams: 2 LiStableNanoporousSilicon.pdf: 3909833 bytes, checksum: 5255c0f044736afaf2aa6ad052f7d040 (MD5) LiStableNanoporousSiliconSupplementFigureS1-S3.pdf: 409282 bytes, checksum: d02612ef153d85f5d449bfd87c452d49 (MD5)

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