Article

 

Solid Solution Studies of Layered Honeycomb-Ordered Phases O3-Na3M2SbO6 (M = Cu, Mg, Ni, Zn) Public Deposited

Analytics

Downloadable Content

Download PDF
https://ir.library.oregonstate.edu/concern/articles/6682x4626

This is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by Elsevier and can be found at:  http://www.journals.elsevier.com/journal-of-solid-state-chemistry/.

Descriptions

Attribute NameValues
Alternative Title
Creator
Abstract
  • Complete solid solutions with the composition Na₃M₂₋ₓM’ₓSbO₆ where M, M’ = Cu, Mg, Ni, Zn have been synthesized by conventional solid state techniques and were investigated using X-ray diffraction, magnetism and optical measurements. All compositions crystallize in a monoclinic unit cell and exhibit a layered structure with a honeycomb cationic ordering within the slabs. These compounds also exhibit Curie-Weiss behavior at high temperatures and the magnetic moment values verify the presence of Cu²⁺ and/or Ni²⁺. The antiferromagnetic order of Na₃Ni₂SbO₆ is suppressed upon substitution of Ni²⁺ with Mg²⁺ or Zn²⁺. The spin gap observed in Na₃Cu₂SbO₆ is also suppressed by substitution of Cu²⁺ with Mg²⁺ or Zn²⁺. The Na₃Ni₂₋ₓCuₓSbO₆ compositions follow an expected transition from an antiferromagnetic ordering to the spin gap of the copper end member. The estimated band gaps for these compounds have been estimated from diffuse reflectance measurements.
Resource Type
DOI
Date Available
Date Issued
Citation
  • Schmidt, W., Berthelot, R., Sleight, A., & Subramanian, M. (2013). Solid solution studies of layered honeycomb-ordered phases O3-Na3M2SbO6 (M = Cu, Mg, Ni, Zn). Journal of Solid State Chemistry, 201, 178-185. doi:10.1016/j.jssc.2013.02.035
Journal Title
Journal Volume
  • 201
Academic Affiliation
Keyword
Rights Statement
Funding Statement (additional comments about funding)
  • This work has been supported by NSF grant DMR 0804167.
Publisher
Peer Reviewed
Language
Replaces
Additional Information
  • description.provenance : Submitted by Deanne Bruner (deanne.bruner@oregonstate.edu) on 2013-07-22T22:09:28Z No. of bitstreams: 1 SubramanianMunirpallamChemistrySolidSolutionStudies.pdf: 1743961 bytes, checksum: 7d58ea56bd8f7972624dfd9291f613bb (MD5)
  • description.provenance : Made available in DSpace on 2013-07-22T22:11:41Z (GMT). No. of bitstreams: 1 SubramanianMunirpallamChemistrySolidSolutionStudies.pdf: 1743961 bytes, checksum: 7d58ea56bd8f7972624dfd9291f613bb (MD5) Previous issue date: 2013-05
  • description.provenance : Approved for entry into archive by Deanne Bruner(deanne.bruner@oregonstate.edu) on 2013-07-22T22:11:41Z (GMT) No. of bitstreams: 1 SubramanianMunirpallamChemistrySolidSolutionStudies.pdf: 1743961 bytes, checksum: 7d58ea56bd8f7972624dfd9291f613bb (MD5)

Relationships

Parents:

This work has no parents.

Items

Thumbnail Title Date Uploaded Visibility Actions
Wp988k537?file=thumbnail SubramanianMunirpallamChemistrySolidSolutionStudies.pdf 2017-07-11 Public