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Rapid Microwave Synthesis of Indium Filled Skutterudites: An energy efficient route to high performance thermoelectric materials

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https://ir.library.oregonstate.edu/concern/articles/9880vr65c

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Abstract
  • Filled skutterudites are promising thermoelectric materials due to reduced thermal conductivity upon inserting a guest atom or 'rattler' into the CoSb₃ structure. By using an indium rattler dimensionless Figure of Merit (ZT) values > 1 at 650 K have been reported. The conventional synthesis of these compounds typically takes several days (~ 3 days) to obtain the final well-sintered material for property measurements. We report here a microwave-assisted synthesis method that reduces the initial calcination time from two days to two minutes. This route significantly reduces the time needed to produce materials suitable for property and device testing.
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Citation
  • K. Biswas, Rapid Microwave Synthesis of Indium Filled Skutterudites: An energy efficient route to high performance thermoelectric materials, Materials Research Bulletin (2010), doi:10.1016/j.materresbull.2011.08.058
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Journal Volume
  • 47
Journal Issue/Number
  • 20
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  • This work was supported by NSF grant DMR 0804167.
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