Synthesis of titanium oxide nanoparticles using DNA-complex as template for solution-processable hybrid dielectric composites Public Deposited

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  • We report the synthesis of TiO₂ nanoparticles prepared by the hydrolysis of titanium isopropoxide (TTIP) in the presence of a DNA complex for solution processable dielectric composites. The nanoparticles were incorporated as fillers in polycarbonate at low concentrations (1.5, 5 and 7 wt%) to produce hybrid dielectric films with dielectric constant higher than thermally grown silicon oxide. It was found that the DNA complex plays an important role as capping agent in the formation and suspension stability of nanocrystalline anatase phase TiO₂ at room temperature with uniform size (~6 nm) and narrow distribution. The effective dielectric constant of spin-cast polycarbonate thin-films increased from 2.84 to 13.43 with the incorporation of TiO₂ nanoparticles into the polymer host. These composites can be solution processed with a maximum temperature of 90 °C and could be potential candidates for its application in low-cost macro-electronics.
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  • Ramos, J. C., Mejia, I., Murphy, J., Quevedo, M., Garcia, P., & Martinez, C. A. (2015). Synthesis of titanium oxide nanoparticles using DNA-complex as template for solution-processable hybrid dielectric composites. Journal of Alloys and Compounds, 643(Supplement 1), S84-S89. doi:10.1016/j.jallcom.2014.09.201
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