Contrasting ion-association behaviour of Ta and Nb polyoxometalates Public Deposited

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  • Small-angle X-ray scattering (SAXS) studies of aqueous [Ta₆O₁₉]⁸⁻ compared to prior studies of aqueous [Nb₆O₁₉]⁸⁻ reveals key differences in behaviour, which is likely at the root of the difficultly in developing polyoxotantalate chemistry. Specifically, where contact ion-pairing dominates between [Nb₆O₁₉]⁸⁻ and its counterions, solvent-separated ion-pairing between [Ta₆O₁₉]⁸⁻ and its counterions has been unveiled in the current study.
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  • Fullmer, L. B., Molina, P. I., Antonio, M. R., & Nyman, M. (2014). Contrasting ion-association behaviour of Ta and Nb polyoxometalates. Dalton Transactions, 43(41), 15295-15299. doi:10.1039/C4DT02394C
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  • description.provenance : Made available in DSpace on 2014-11-11T19:35:59Z (GMT). No. of bitstreams: 2 FullmerLaurenChemistryContrastingIonAssociation.pdf: 1198509 bytes, checksum: c05772702db309cdbc4fd4de09538065 (MD5) FullmerLaurenChemistryContrastingIonAssociation_SupportingInformation.pdf: 3519880 bytes, checksum: 8a38a1fcccd20e72bd4a16cea1e3ada2 (MD5) Previous issue date: 2014-11-07
  • description.provenance : Submitted by Erin Clark (erin.clark@oregonstate.edu) on 2014-11-11T19:35:09Z No. of bitstreams: 2 FullmerLaurenChemistryContrastingIonAssociation.pdf: 1198509 bytes, checksum: c05772702db309cdbc4fd4de09538065 (MD5) FullmerLaurenChemistryContrastingIonAssociation_SupportingInformation.pdf: 3519880 bytes, checksum: 8a38a1fcccd20e72bd4a16cea1e3ada2 (MD5)
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