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Contrasting ion-association behaviour of Ta and Nb polyoxometalates Public Deposited

https://ir.library.oregonstate.edu/concern/articles/cj82k922d

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Abstract
  • Small-angle X-ray scattering (SAXS) studies of aqueous [Ta₆O₁₉]⁸⁻ compared to prior studies of aqueous [Nb₆O₁₉]⁸⁻ reveals key differences in behaviour, which is likely at the root of the difficultly in developing polyoxotantalate chemistry. Specifically, where contact ion-pairing dominates between [Nb₆O₁₉]⁸⁻ and its counterions, solvent-separated ion-pairing between [Ta₆O₁₉]⁸⁻ and its counterions has been unveiled in the current study.
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  • Fullmer, L. B., Molina, P. I., Antonio, M. R., & Nyman, M. (2014). Contrasting ion-association behaviour of Ta and Nb polyoxometalates. Dalton Transactions, 43(41), 15295-15299. doi:10.1039/C4DT02394C
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  • 43
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  • 41
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  • The work at Oregon State University was supported by the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering under Award # DE-SC0010802TDD. The work at Argonne National Laboratory—including the use of the Advanced Photon Source, an Office of Science User Facility operated for the U.S. Department of Energy (DOE) Office of Science by Argonne National Laboratory—was supported by the U.S. DOE under Contract No. DE-AC02-06CH11357.
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  • description.provenance : Made available in DSpace on 2014-11-11T19:35:59Z (GMT). No. of bitstreams: 2 FullmerLaurenChemistryContrastingIonAssociation.pdf: 1198509 bytes, checksum: c05772702db309cdbc4fd4de09538065 (MD5) FullmerLaurenChemistryContrastingIonAssociation_SupportingInformation.pdf: 3519880 bytes, checksum: 8a38a1fcccd20e72bd4a16cea1e3ada2 (MD5) Previous issue date: 2014-11-07
  • description.provenance : Submitted by Erin Clark (erin.clark@oregonstate.edu) on 2014-11-11T19:35:09Z No. of bitstreams: 2 FullmerLaurenChemistryContrastingIonAssociation.pdf: 1198509 bytes, checksum: c05772702db309cdbc4fd4de09538065 (MD5) FullmerLaurenChemistryContrastingIonAssociation_SupportingInformation.pdf: 3519880 bytes, checksum: 8a38a1fcccd20e72bd4a16cea1e3ada2 (MD5)
  • description.provenance : Approved for entry into archive by Erin Clark(erin.clark@oregonstate.edu) on 2014-11-11T19:35:59Z (GMT) No. of bitstreams: 2 FullmerLaurenChemistryContrastingIonAssociation.pdf: 1198509 bytes, checksum: c05772702db309cdbc4fd4de09538065 (MD5) FullmerLaurenChemistryContrastingIonAssociation_SupportingInformation.pdf: 3519880 bytes, checksum: 8a38a1fcccd20e72bd4a16cea1e3ada2 (MD5)

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