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FullmerLaurenChemistryContrastingIonAssociation.pdf

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https://ir.library.oregonstate.edu/concern/articles/k0698932z

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  • Small-angle X-ray scattering (SAXS) studies of aqueous [Ta₆O₁₉]⁸⁻ compared to prior studies of aqueous [Nb₆O₁₉]⁸⁻ reveals key differences in behaviour, which is likely at the root of the difficultly in developing polyoxotantalate chemistry. Specifically, where contact ion-pairing dominates between [Nb₆O₁₉]⁸⁻ and its counterions, solvent-separated ion-pairing between [Ta₆O₁₉]⁸⁻ and its counterions has been unveiled in the current study.
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file details FullmerLaurenChemistryContrastingIonAssociation.pdf 2017-07-26 Público Baixar